Abstract:

Nanoaluminum was subjected to surface activation using sodium hydroxide(NaOH)solution.In order to introduce epoxy group onto the surface of nanoaluminum, γglycidoxypropy1 trimethoxysilane(KH560)and EP resin were used for surface treatment after the activation process.The effect of activated nanoaluminum and epoxy functionalized nanoaluminum on the mechanism and kinetic parameters of curing reaction of epoxy resin were studied by means of nonisothermal differential scanning calorimetry(DSC).The relationship between activation energy and conversion of the curing reaction was determined by using the isoconversional methods of Friedman and KAS, and the kinetics parameters were also obtained by using Kissinger equation.The results showed that the existence of activated nanoaluminum and epoxy functionalized nanoaluminum increased the rate constant and decreased gelling temperature.The addition of activated nanoaluminum and epoxy functionalized nanoaluminum increased activation energy and dealing temperature.When 2% KH560 modified nanoaluminum was used, gelling temperature decreased 6.5℃, and dealing temperature increased 17.5℃, but has no obvious effect on the order of reaction and did not change the overall curing reaction mechanism.

Key words: 环氧树脂, 活化纳米氧化铝, 固化动力学, 等转化率法

摘要：

采用氢氧化钠溶液将纳米氧化铝表面活化，利用γ缩水甘油醚氧丙基三甲氧基硅烷（KH560）和环氧树脂对活化纳米氧化铝进行表面处理而引入环氧基团。采用差示扫描量热法（DSC）研究复合材料的非等温固化行为，分析了活化纳米氧化铝及其环氧功能化产物对环氧树脂固化动力学参数与机理的影响，运用等转化率方法包括Friedman方法与KAS方法研究了复合材料固化活化能与转化率的关系。实验结果表明，活化纳米氧化铝及其环氧功能化产物降低了固化体系的理论凝胶温度，对固化反应有促进作用；纳米氧化铝的加入使固化反应活化能增大，后固化温度提高，当加入2%的KH560改性活化纳米氧化铝，凝胶温度降低了6.5℃，而后固化温度提高了17.5℃，但对反应级数影响不大。

关键词: 环氧树脂, 活化纳米氧化铝, 固化动力学, 等转化率法