• 热力学 • Previous Articles     Next Articles

CALCULATION OF CONDUCTANCE FOR ORGANIC SOLUTIONS OF LITHIUM SALT USING MEAN SPHERICAL APPROXIMATION THEORY

HAN Jingli   

  • Online:2004-02-25 Published:2004-02-25

应用平均球近似理论计算锂盐有机溶液电导率

韩景立   

  1. 清华大学化学工程系,北京100084

Abstract: The molar conductance of electrolytes LiPF6-PC(propylene carbonate), LiPF6•2DG(diglyme)-PC and LiPF6•PMDETA(pentamethyldiethylenetriamine)-PC were calculated by using mean spherical approximation(MSA). The range of concentration was from 0.001 mol•L-1 to 1 mol•L-1. The dissociation equilibrium of salts is taken into account. The mean relative deviations were 5.6%, 4.2% and 4.7%, respectively.