CIESC Journal

• 化工学报 • 上一篇    下一篇

固液界面高分子吸附研究(Ⅱ)──高分子在界面的吸附

王相田,胡英   

  1. 华东理工大学技术化学物理研究所、国家超细粉末中心!上海200237,华东理工大学化学系!上海200237
  • 出版日期:1998-08-25 发布日期:1998-08-25

ASTUDY ON ADSORPTION OF POLYMER AT THE SOLID/LIQUID INTERFACE(Ⅱ)──ADSORPTION BEHAVIOR OF POLYMER

Wang Xiangtian;Hu Ying (Institute of Technical Chemistry and Physics,ECUST,Shanghai 200237)(Department of Chemistry,ECUST,Shanghai 200237)   

  • Online:1998-08-25 Published:1998-08-25

摘要: 用本文(I)报建立的高分子吸附模型,计算了高分子在界面区的浓度分布、高分子吸附层的厚度、吸附量、不同构型的链段长度及其分布等微观结构,考察了体相高分子浓度、高分子──溶剂相互作用参数、吸附能参数、高分子链长等对高分子吸附行为的影响.

Abstract: The adsorption models of polymer at the solid/liquid interfaces developed in the previous paper were used to calculate the microscopic structrues of the polymer adsorption layers including polymer concentration profile in the region of the interface,thickness of adsorption layer,adsorption amout,and distributions and average lengths of chain configurations of train,loop and tail configurations.The influence on adsoprtion behavior by bulk polymer concentration,interaction parameter between polymer and solvent,adsoprtion energy parameter and chain length was investigated.

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