高抗冲聚丙烯颗粒的流动性及其抗静电性

doi:10.11949/j.issn.0438-1157.20161037

化工学报 ›› 2017, Vol. 68 ›› Issue (2): 767-773.DOI: 10.11949/j.issn.0438-1157.20161037

• 材料化学工程与纳米技术 • 上一篇下一篇

高抗冲聚丙烯颗粒的流动性及其抗静电性

徐宏彬¹, 陈薇², 武燕², 梅利¹, 姚臻², 笪文忠¹, 曹堃²

1. 中国石化扬子石油化工有限公司南京研究院, 江苏南京 210047;
2. 化学工程联合国家重点实验室, 浙江大学化学工程与生物工程学院, 浙江杭州 310027

收稿日期:2016-07-22 修回日期:2016-11-05 出版日期:2017-02-05 发布日期:2017-02-05
通讯作者: 曹堃
基金资助:
国家高技术研究发展计划项目（2012AA040306）。

Flowability and anti-static properties of high impact polypropylene particles

XU Hongbin¹, CHEN Wei², WU Yan², MEI Li¹, YAO Zhen², DA Wenzhong¹, CAO Kun²

1. Nanjing Research Institute of SINOPEC Yangzi Petrochemical Company Limited, Nanjing 210047, Jiangsu, China;
2. State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China

Received:2016-07-22 Revised:2016-11-05 Online:2017-02-05 Published:2017-02-05
Supported by:
supported by the National High Technology Research Program of China (2012AA040306).

摘要/Abstract

摘要：

随着气相釜中乙烯含量的增加，高抗冲聚丙烯颗粒会出现发黏、聚并等现象，严重影响其流动性及连续化生产。添加极少量惰性无机超细粉体是减少高抗冲聚丙烯颗粒间粘连的有效措施。通过冷模研究，剖析超细粉体的加入对颗粒流动性的影响，同时探讨体系静电的产生因素及其对颗粒流动性的影响。选用的超细粉体包括球形二氧化硅和层状水滑石。研究发现，相对于直接加入未改性处理的超细粉体，加入经抗静电剂改性的超细粉体后，颗粒的带电量明显减少，落下时间缩短，流动性也得到了有效提高；而且选用水滑石的效果明显优于二氧化硅。

关键词: 高抗冲聚丙烯, 超细粉体, 抗静电剂, 流动性

Abstract:

With the increase of ethylene content in gas phase fluidized bed, stickiness and agglomeration among high impact polypropylene granules seriously impacted on particle flowability and continuous production. Adding a small amount of inert inorganic superfine powders could effectively reduce the sticky agglomeration. The cold-flow model study was to analyze impact of superfine powders such as spherical silica and layered hydrotalcite (HT), as well as to explore electrostatic formation and effect on flowability. Compared to untreated powders, powders modified by antistatic agents could decrease accumulation of static charges, shorten dropping time, and enhance flowability of particles. Overall, hydrotalcite showed better effect than silica.

Key words: high impact polypropylene, superfine powder, antistatic agent, flowability

中图分类号:

TQ033

徐宏彬, 陈薇, 武燕, 梅利, 姚臻, 笪文忠, 曹堃. 高抗冲聚丙烯颗粒的流动性及其抗静电性[J]. 化工学报, 2017, 68(2): 767-773.

XU Hongbin, CHEN Wei, WU Yan, MEI Li, YAO Zhen, DA Wenzhong, CAO Kun. Flowability and anti-static properties of high impact polypropylene particles[J]. CIESC Journal, 2017, 68(2): 767-773.

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高抗冲聚丙烯颗粒的流动性及其抗静电性

Flowability and anti-static properties of high impact polypropylene particles

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