化工学报 ›› 2013, Vol. 64 ›› Issue (5): 1876-1883.DOI: 10.3969/j.issn.0438-1157.2013.05.051

• 材料化学工程与纳米技术 • 上一篇    下一篇

聚丙烯酸酯/铜酞菁蓝复合乳胶膜中颜料颗粒的分散状态

戚栋明1, 徐杰1, 陈智杰1, 杨雷1, 吴明华1, 郭文登2   

  1. 1. 浙江理工大学生态染整技术教育部工程研究中心, 先进纺织材料与制备技术教育部重点实验室, 浙江 杭州 310018;
    2. 浙江华泰丝绸有限公司, 浙江 杭州 310011
  • 收稿日期:2012-09-27 修回日期:2012-11-27 出版日期:2013-05-05 发布日期:2013-05-05
  • 通讯作者: 戚栋明
  • 作者简介:戚栋明(1978-),男,副教授。
  • 基金资助:

    国家自然科学基金项目(50803058,51273182);浙江省自然科学基金项目(Y4100221);浙江省重点创新团队资助项目(2010R50038)。

Dispersion of pigment particles in polyacrylate latex film containing phthalocyanine blue

QI Dongming1, XU Jie1, CHEN Zhijie1, YANG Lei1, WU Minghua1, GUO Wendeng2   

  1. 1. Engineering Research Center of Ecological Dyeing and Finishing Technology, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, Zhejiang, China;
    2. Zhejiang Huatai Silk Co., Ltd., Hangzhou 310011, Zhejiang, China
  • Received:2012-09-27 Revised:2012-11-27 Online:2013-05-05 Published:2013-05-05
  • Supported by:

    supported by the National Natural Science Foundation of China(50803058,51273182),the Natural Science Foundation of Zhejiang Province(Y4100221) and Zhejiang Provincial Key Innovation Team(2010R50038).

关键词: 乳胶膜, 成膜机制, 分散性, 有机颜料

Abstract: Pigmented latex films were formed from organic pigment phthalocyanine blue and ultrasonic blended latex containing butyl acrylate-styrene copolymer latex(abbreviated as PA+PB)and composite latex prepared via mini-emulsion polymerization(abbreviated as PA/PB)at room temperature respectively and then the films were cured at 120℃.Morphology of pigmented latexes, pigment dispersion in the interior and on the surface of latex films, and color of pigmented latexes were analyzed by DLS, FE-SEM,(Section)-TEM and spectrophotometry.The film formation mechanisms of two kinds of pigmented latexes were studied and compared.It was found that, the binding capacity between pigment and adhesive in blended latex PA+PB were poor.Migration and aggregation of pigment particles would generally occur during film formation, and thus many loose pigment aggregations at micron size could be formed on the surface and in the interior of pigmented latex.In composite latex PA/PB, pigment particles were pre-encapsulated in the interior of quasi-nanoscale adhesive particles.This microcapsule structure led to less obvious effect of pigment particles on film formation.Thus the size of pigment aggregate could be controlled on quasi-nanoscale, and almost all pigment particles could be dispersed in the whole film at the primary particle level.This would give the composite latex PA/PB film better color depth, color fastness and color uniformity.

Key words: latex film, film formation mechanism, dispersion, organic pigment

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