聚丙烯酸酯/铜酞菁蓝复合乳胶膜中颜料颗粒的分散状态

doi:10.3969/j.issn.0438-1157.2013.05.051

化工学报 ›› 2013, Vol. 64 ›› Issue (5): 1876-1883.DOI: 10.3969/j.issn.0438-1157.2013.05.051

• 材料化学工程与纳米技术 • 上一篇下一篇

聚丙烯酸酯/铜酞菁蓝复合乳胶膜中颜料颗粒的分散状态

戚栋明¹, 徐杰¹, 陈智杰¹, 杨雷¹, 吴明华¹, 郭文登²

1. 浙江理工大学生态染整技术教育部工程研究中心, 先进纺织材料与制备技术教育部重点实验室, 浙江杭州 310018;
2. 浙江华泰丝绸有限公司, 浙江杭州 310011

收稿日期:2012-09-27 修回日期:2012-11-27 出版日期:2013-05-05 发布日期:2013-05-05
通讯作者: 戚栋明
作者简介:戚栋明(1978-),男,副教授。
基金资助:
国家自然科学基金项目(50803058,51273182);浙江省自然科学基金项目(Y4100221);浙江省重点创新团队资助项目(2010R50038)。

Dispersion of pigment particles in polyacrylate latex film containing phthalocyanine blue

QI Dongming¹, XU Jie¹, CHEN Zhijie¹, YANG Lei¹, WU Minghua¹, GUO Wendeng²

1. Engineering Research Center of Ecological Dyeing and Finishing Technology, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, Zhejiang, China;
2. Zhejiang Huatai Silk Co., Ltd., Hangzhou 310011, Zhejiang, China

Received:2012-09-27 Revised:2012-11-27 Online:2013-05-05 Published:2013-05-05
Supported by:
supported by the National Natural Science Foundation of China(50803058,51273182),the Natural Science Foundation of Zhejiang Province(Y4100221) and Zhejiang Provincial Key Innovation Team(2010R50038).

摘要/Abstract

关键词: 乳胶膜, 成膜机制, 分散性, 有机颜料

Abstract: Pigmented latex films were formed from organic pigment phthalocyanine blue and ultrasonic blended latex containing butyl acrylate-styrene copolymer latex(abbreviated as PA+PB)and composite latex prepared via mini-emulsion polymerization(abbreviated as PA/PB)at room temperature respectively and then the films were cured at 120℃.Morphology of pigmented latexes, pigment dispersion in the interior and on the surface of latex films, and color of pigmented latexes were analyzed by DLS, FE-SEM,(Section)-TEM and spectrophotometry.The film formation mechanisms of two kinds of pigmented latexes were studied and compared.It was found that, the binding capacity between pigment and adhesive in blended latex PA+PB were poor.Migration and aggregation of pigment particles would generally occur during film formation, and thus many loose pigment aggregations at micron size could be formed on the surface and in the interior of pigmented latex.In composite latex PA/PB, pigment particles were pre-encapsulated in the interior of quasi-nanoscale adhesive particles.This microcapsule structure led to less obvious effect of pigment particles on film formation.Thus the size of pigment aggregate could be controlled on quasi-nanoscale, and almost all pigment particles could be dispersed in the whole film at the primary particle level.This would give the composite latex PA/PB film better color depth, color fastness and color uniformity.

Key words: latex film, film formation mechanism, dispersion, organic pigment

中图分类号:

TQ32517

戚栋明, 徐杰, 陈智杰, 杨雷, 吴明华, 郭文登. 聚丙烯酸酯/铜酞菁蓝复合乳胶膜中颜料颗粒的分散状态[J]. 化工学报, 2013, 64(5): 1876-1883.

QI Dongming, XU Jie, CHEN Zhijie, YANG Lei, WU Minghua, GUO Wendeng. Dispersion of pigment particles in polyacrylate latex film containing phthalocyanine blue[J]. CIESC Journal, 2013, 64(5): 1876-1883.

参考文献 14

[1]	Zhou Shuxue, Wu Limin, You Bo, Gu Guangxin.Smart Coatings(Ⅱ):Preparation, Structure and Properties of Organic-Inorganic Nanocomposite Coatings[M].New York:American Chemical Society, 2009:193-219
[2]	Ma Y, Davis H T, Scriven L E.Microstructure development in drying latex coatings[J].Prog. Org. Coat., 2005, 52:46-62
[3]	Schmid A,Scherl P,Armes S P, Leite C, Galembeck F.Synthesis and characterization of film-forming colloidal nanocomposite particles prepared via surfactant-free aqueous emulsion copolymerization[J].Macromolecules, 2009, 42:3721-3728
[4]	Qi Dongming(戚栋明), Bao Yongzhong(包永忠), Huang Zhiming(黄志明), Weng Zhixue(翁志学).Anchoring of polyacrylate onto silica and formation of polyacrylate/silica nanocomposite particles via in-situ emulsion polymerization[J]. Colloid Polym. Sci.,2008,284:233-241
[5]	Lee A Fielding, Jeff Tonnar, Steven P Armes.All-acrylic film-forming colloidal polymer/silica nanocomposite particles prepared by aqueous emulsion polymerization[J].Langmuir, 2011, 27:11129-11144
[6]	Elodie Bourgeat-Lami,Muriel Lansalot.Organic/inorganic composite latexes:the marriage of emulsion polymerization and inorganic chemistry[J].Adv. Polym. Sci., 2010,233:53-123
[7]	Norma Negrete-Herrera, Jean-Luc Putaux,Laurent David,Felix de Haas,Elodie Bourgeat-Lami. Polymer/Laponite composite latexes:particle morphology, film microstructure, and properties[J].Macromol. Rapid Comm., 2007, 28:1567-1573
[8]	Qi Dongming(戚栋明), Zhang Rui(张睿), Xu Lingyu(许玲玉), Yuan Yan(袁艳), Lei Lin(雷琳).Preparation and characterization of organic pigment phthalocyanine blue microcapsules by in situ micro-suspensionpolymerization[J].Acta Polymerica Sinica(高分子学报), 2011(2):145-150
[9]	Chen Zhijie(陈智杰), Shen Xingcong(申兴丛), Xu Jie(徐杰), Xu Lingyu(许玲玉), Qi Dongming(戚栋明).Effect of morphology of microcapsulated natural pigment on printing result of cotton fabrics[J].Journal of Textile Research(纺织学报), 2011, 32(8):81-86, 91
[10]	Qi Dongming(戚栋明), Chen Zhijie(陈智杰), Zhao Xiaoli(赵晓丽), Xu Jie(徐杰), Shen Xingcong(申兴丛), Yang Lei(杨雷).Performance of new flotation system based on high dissolved air content[J].CIESC Journal(化工学报),2013,64(3):1118-1123
[11]	Lei Lin(雷琳), Lü Nana(吕娜娜), Wu Minghua(吴明华), Qi Dongming(戚栋明).De-aggregation of nano-TiO2 soft agglomeration in aqueous medium[J].CIESC Journal(化工学报), 2009, 60(12):3159-3164
[12]	Zhang S,et al.Fabrication of ordered porous polymer film via a one-step strategy and its formation mechanism[J].Macromolecules, 2009, 42(10):3591-3597
[13]	Patel Milan J, Gundabala Venkata R, Routh Alexander F. Modeling film formation of polymer-clay nanocomposite particles[J].Langmuir, 2010,26(6):3962-3971
[14]	Feng Jianrong,Winnik Mitchell A,Shivers Richard R,Clubb Brian.Polymer blend latex films:morphology and transparency[J].Macromolecules, 1995,28(23):7671-7682

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聚丙烯酸酯/铜酞菁蓝复合乳胶膜中颜料颗粒的分散状态

Dispersion of pigment particles in polyacrylate latex film containing phthalocyanine blue

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