改性聚乙烯填料CANON反应器的启动与运行

doi:10.3969/j.issn.0438-1157.2014.11.027

化工学报 ›› 2014, Vol. 65 ›› Issue (11): 4406-4412.DOI: 10.3969/j.issn.0438-1157.2014.11.027

• 催化、动力学与反应器 • 上一篇下一篇

改性聚乙烯填料CANON反应器的启动与运行

付昆明^1,2, 张杰², 曹相生², 李冬², 左早荣¹, 王会芳¹

1. 北京建筑大学环境与能源工程学院, 城市雨水系统与水环境省部共建教育部重点实验室, 北京 100044;
2. 北京工业大学水质科学与水环境恢复工程北京市重点实验室, 北京 100124

收稿日期:2014-04-28 修回日期:2014-07-22 出版日期:2014-11-05 发布日期:2014-11-05
通讯作者: 付昆明
基金资助:
国家自然科学基金项目(51308025);北京高等学校青年英才计划项目(YETP1649).

Start-up of CANON reactor with modified polyethylene carrier and its performance

FU Kunming^1,2, ZHANG Jie², CAO Xiangsheng², LI Dong², ZUO Zaorong¹, WANG Huifang¹

1. Key Laboratory of Urban Storm Water System and Water Environment, Ministry of Education, School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China;
2. Key Laboratory of Beijing for Water Quality Science and Water Environmental Recovery Engineering, School of Architecture and Civil Engineering, Beijing University of Technology, Beijing 100124, China

Received:2014-04-28 Revised:2014-07-22 Online:2014-11-05 Published:2014-11-05
Supported by:
supported by the National Natural Science Foundation of China (51308025), Beijing Higher Education Young Elite Teacher Project (YETP1649).

摘要/Abstract

摘要： 以人工配制无机高氨氮废水为进水,通过接种CANON污泥,研究了改性聚乙烯填料CANON反应器的启动过程.为避免初期溶解氧的抑制作用, 启动采用先厌氧后好氧的方式,以加速ANAMMOX细菌的增殖.首先,在室温[(20±5)℃]、厌氧条件下,历经300 d依然不能启动厌氧氨氧化,TN去除负荷仅为0.12 kg·(m³·d)^-1;当提高温度至30℃后,30 d后,TN的去除负荷达到0.23 kg·(m³·d)^-1;改为好氧条件后,经过38 d后,TN的去除负荷达到1.01 kg·(m³·d)^-1,TN去除率达到77.61%, 的平均值为0.122,接近理论值0.127,表明CANON反应器的脱氮效果良好,短程硝化稳定.通过分析认为,采用先厌氧后好氧的方式启动,并没有达到加速培养ANAMMOX细菌的预期目的,改性聚乙烯填料不适用在厌氧条件下培养ANAMMOX细菌.改性聚乙烯填料CANON反应器启动成功后,需要的曝气量少,但运行不易稳定,应对于CANON反应器形式予以改进,建议将改性聚乙烯填料结合UASB反应器采用,使污泥免于流失.

关键词: CANON工艺, 改性聚乙烯, 厌氧氨氧化, 短程硝化, 氨氮

Abstract: A CANON reactor with modified polyethylene carrier was started up by seeding sludge from another mature CANON reactor and using artificial inorganic ammonia-rich waste water as influent. To accelerate ANAMMOX bacteria cultivation, the start-up was under anaerobic conditions first to avoid dissolved oxygen inhibition on ANAMMOX bacteria, and then under aerobic conditions. The reactor was first under anaerobic conditions to start ANAMMOX process at room temperature [(20±5)℃] in first 300 days, however, total nitrogen removal load was only 0.12 kg·(m³·d)^-1, which meant failure of ANAMMOX. When temperature was increased to 30℃, 30 days later, total nitrogen removal load was up to 0.23 kg·(m³·d)^-1. Then anaerobic conditions was changed to aerobic conditions, and total nitrogen removal load was up to 1.01 kg·(m³·d)^-1, while nitrogen removal efficiency was 77.61%, and average variation ratio of nitrate and nitrogen (δNO₃^--N/δTN) was 0.122, close to theoretical value 0.127, showing both good stability of nitritation and good nitrogen removal. Adopting the way of anaerobic stage first and then aerobic stage could not accelerate ANAMMOX bacteria cultivation as expected, and modified polyethylene carrier was not a suitable carrier to start ANAMMOX process under anaerobic conditions. However, once the reactor was successfully started up, aeration could be saved, though it might perform unstably. Modified polyethylene carrier was suggested to combine with UASB reactor to keep bacteria.

Key words: CANON process, modified polyethylene, ANAMMOX, nitritation, ammonia

中图分类号:

X703

付昆明, 张杰, 曹相生, 李冬, 左早荣, 王会芳. 改性聚乙烯填料CANON反应器的启动与运行[J]. 化工学报, 2014, 65(11): 4406-4412.

FU Kunming, ZHANG Jie, CAO Xiangsheng, LI Dong, ZUO Zaorong, WANG Huifang. Start-up of CANON reactor with modified polyethylene carrier and its performance[J]. CIESC Journal, 2014, 65(11): 4406-4412.

参考文献 20

[1]	Sliekers A O, Derwort N, Campos-Gomez J L, et al. Completely autotrophic nitrogen removal over nitrite in one single reactor [J]. Water Research, 2002, 36 (10): 2475-2482
[2]	Strous M, Fuerst J A, Kramer E H, Logemann S, Muyzer G, van de Pas-Schoonen K T, Webb R, Kuenen J G, Jetten M S. Missing lithotroph identified as new planctomycete [J]. Nature, 1999, 400 (6743): 446-449
[3]	Strous M, Heijnen J J, Kuenen J G, et al. The sequencing batch reactor as a powerful tool for the study of slowly growing anaerobic ammonium-oxidizing microorganisms [J]. Applied Microbiology and Biotechnology, 1998, 50 (5): 589-596
[4]	Fu Kunming (付昆明), Zhang Jie (张杰), Cao Xiangsheng (曹相生), Li Dong (李冬), Meng Xuezheng (孟雪征), Zhu Zhaoliang (朱兆亮). Study of CANON process start-up under aerobic conditions [J]. Environmental Science (环境科学), 2009, 30 (6): 1689-1694
[5]	Fu Kunming (付昆明). Start-up and performance of nitrogen removal of CANON reactor [D]. Beijing: Beijing University of Technology, 2010
[6]	Liu Tao (刘涛),Li Dong (李冬),Zeng Huiping (曾辉平),Zhang Jie (张杰). Distribution of functional bacteria alone bio-filter of CANON reactor at room temperature [J]. Journal of Harbin Institute of Technology (哈尔滨工业大学学报), 2012, 44 (10): 22-27
[7]	Liu S, Yang F, Gong Z, Su Z. Assessment of the positive effect of salinity on the nitrogen removal performance and microbial composition during the start-up of CANON process [J]. Applied Microbiology and Biotechnology, 2008, 80 (2): 339-348
[8]	Furukawa K, Lieu P, Tokitoh H, Fujii T. Development of single-stage nitrogen removal using ANAMMOX and partial nitritation (SNAP) and its treatment performances [J]. Water Science & Technology, 2006, 53 (6): 83-90
[9]	Liao Dexiang (廖德祥), Li Xiaoming (李小明), Zeng Guangming (曾光明), Yang Qi (杨麒), Yang Guojing (杨国靖). Studies on deammonification process in single SBR biofilm [J]. China Environmental Science (中国环境科学), 2005, 25 (2): 222-225
[10]	Vázquez-Padín J R, Pozo M J, Jarpa M, Figueroa M, Franco A, Mosquera-Corral A, Campos J L, Méndez R. Treatment of anaerobic sludge digester effluents by the CANON process in an air pulsing SBR [J]. Journal of Hazardous Materials, 2009, 166 (1): 336-341
[11]	Qiao S, Kawakubo Y, Cheng Y, Nishiyama T, Fujii T, Furukawa K. ANAMMOX process for synthetic and practical wastewater treatment using a novel kind of biomass carriers [J]. Water Science & Technology, 2008, 58 (6): 1335-1341
[12]	Lackner S, Gilbert E M, Vlaeminck S E, Joss A, Horn H, van Loosdrecht M C M. Full-scale partial nitritation/ANAMMOX experiences—an application survey [J]. Water Research, 2014, 55: 292-303
[13]	Ministry of Environmental Protection of the People's Republic of China (中华人民共和国环境保护部). The Methods of Water and Wastewater Monitor (水和废水监测分析方法) [M]. 4th ed. Beijing: China Environmental Science Press, 2012
[14]	Ministry of Health of the People's Republic of China (中华人民共和国卫生部). GB/T 5750.5—2006 [S]
[15]	Strous M, Kuenen J G, Jetten M. Key physiology of anaerobic ammonium oxidation [J]. Applied and Environmental Microbiology, 1999, 65 (7): 3248-3250
[16]	Fu Kunming (付昆明) , Zhang Jie (张杰), Cao Xiangsheng (曹相生) , Li Dong (李冬), Meng Xuezheng (孟雪征). Performance stability of CANON reactor and temperature impact [J]. Environmental Science (环境科学), 2012, 33 (10): 3507-3512
[17]	Strous M, van Gerven E, Kuenen J G, Jetten M. Effects of aerobic and microaerobic conditions on anaerobic ammonium-oxidizing (ANAMMOX) sludge [J]. Applied and Environmental Microbiology, 1997, 63 (6): 2446- 2448
[18]	Liu T, Li D, Zeng H P, Chang X Y, Zhang J. Microbial characteristics of a CANON reactor during the start-up period seeding conventional activated sludge [J]. Water Science & Technology, 2013, 67 (3): 635-643
[19]	Fu Kunming (付昆明), Zuo Zaorong (左早荣), Qiu Fuguo (仇付国). Start-up by inoculation and operation of a CANON reactor with haydite as the carrier [J]. Environmental Science (环境科学), 2014, 35 (3): 995-1001
[20]	Fu Kunming (付昆明), Zhang Jie (张杰), Cao Xiangsheng (曹相生), Li Dong (李冬), Meng Xuezheng (孟雪征), Zhu Zhaoliang (朱兆亮). Effect of aeration rate on CANON reactors with different carriers [J]. CIESC Journal (化工学报), 2010, 61 (2): 496-503

改性聚乙烯填料CANON反应器的启动与运行

Start-up of CANON reactor with modified polyethylene carrier and its performance

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 20

相关文章 15

编辑推荐

Metrics

本文评价

[1]	孙雅, 周通, 陈广源, 季琳安, 吉远辉, 陆小华, 王昌松. 鸟粪石晶体生长速率关键影响因素的定量分析[J]. 化工学报, 2021, 72(11): 5831-5839.
[2]	耿莉莉, 杨凯旭, 张诺伟, 陈秉辉. Ru和Cu协同催化湿式氧化处理氨氮废水[J]. 化工学报, 2018, 69(9): 3869-3878.
[3]	杨庆, 杨玉兵, 李健敏, 冯红利, 周薛扬, 刘秀红. 短程硝化耦合厌氧氨氧化工艺处理低C/N比生活污水[J]. 化工学报, 2018, 69(8): 3635-3642.
[4]	汪宗御, 邝海浪, 张继锋, 纪玉龙. 基于DOC+SCR的船用柴油机尾气污染物脱除实验[J]. 化工学报, 2018, 69(7): 3249-3256.
[5]	陈希, 王建芳, 钱飞跃, 高军军, 沈耀良, 周丰. 连续流与序批式组合运行启动高性能CANON反应器[J]. 化工学报, 2018, 69(4): 1695-1702.
[6]	何佳敏, 孟佳, 张永, 李建政. 温度降低对UMSR处理高氨氮低碳氮比养猪废水效能的影响[J]. 化工学报, 2017, 68(5): 2074-2080.
[7]	杨庆, 周桐, 刘秀红, 李海鑫, 李健敏, 余飞, 彭永臻. 常温下接种回流污泥实现BAF一体化自养脱氮工艺[J]. 化工学报, 2017, 68(5): 2081-2088.
[8]	高梦佳, 王淑莹, 王衫允, 彭永臻. 生活污水对成熟厌氧氨氧化颗粒污泥的影响[J]. 化工学报, 2017, 68(5): 2066-2073.
[9]	韩红桂, 陈治远, 乔俊飞, 张会清. 基于区间二型模糊神经网络的出水氨氮软测量[J]. 化工学报, 2017, 68(3): 1032-1040.
[10]	曹丽娟, 陈杰, 姜广萌, 常青龙, 王亚宜. 基于侧流富集/主流强化的CANON工艺处理常温低氨氮废水的稳态控制[J]. 化工学报, 2017, 68(12): 4723-4730.
[11]	宿程远, 卢宇翔, 覃菁菁, 黄梅, 郑鹏, 林香凤, 黄智. 不同氨氮含量对厌氧颗粒污泥理化特性的影响[J]. 化工学报, 2017, 68(12): 4784-4792.
[12]	王成, 孟佳, 李玖龄, 李建政, 赵贞. 升流式微氧生物膜反应器处理高氨氮低C/N比养猪废水的效能[J]. 化工学报, 2016, 67(9): 3895-3901.
[13]	张方斋, 王淑莹, 彭永臻, 苗蕾, 曹天昊, 王众. CANON工艺处理实际晚期垃圾渗滤液的启动实验[J]. 化工学报, 2016, 67(9): 3910-3918.
[14]	谢丽, 殷紫, 尹志轩, 王悦超, 周琪. 一段式厌氧氨氧化工艺亚硝酸盐氧化菌抑制方法研究进展[J]. 化工学报, 2016, 67(7): 2647-2655.
[15]	赵梦月, 彭永臻, 王博, 郭媛媛. SBR工艺实现长期稳定的部分短程硝化[J]. 化工学报, 2016, 67(6): 2525-2532.