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Lurgi型甲醇合成反应器的模型化(Ⅰ)MK-101型催化剂上合成甲醇的宏观动力学

张存旺,李成岳   

  1. 北京石油化工学院化工系!北京102600,北京化工学院化工系!北京100029
  • 出版日期:1994-08-25 发布日期:1994-08-25

MODELING OF LURGI-TYPE REACTOR FOR METHANOL SYNTHESIS ( I )APPARENT KINETICS OF METHANOL SYNTHESIS ON MK -101 TYPE CATALYST

Zhang Cunwang(Department of Chemical Engineering,Beijing Institute of Petrochemical Technology,Beijing, 102600)Li Chengyue(Department of Chemical Engineering,Beijing Institute of Chemical Technology,Beijing, 100029)   

  • Online:1994-08-25 Published:1994-08-25

PDF (PC)

132

被引次数

10 | 2

摘要： 在接近工业操作的条件下,采用内循环无梯度反应器,对在原粒度MK-101催化剂上由CO/CO_2/H_2合成甲醇的宏观动力学进行了实验研究,获得了可供实用的宏观动力学方程.研究表明,合成甲醇与变换反应的循环偶合是这一复杂反应体系最显著的动力学特征.

Abstract: The apparent kinetics of methanol synthesis from the gas mixtures containing CO, CO2 and H2 was studied in an internal recycle gradientless reactor. A commercial copper based catalyst, in full size particle form, was used with the experimental conditions similar to the operation range of an industrial reactor. The kinetic performance of the reaction system is described in terms of the rate expressions of two reactions.

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