Ag/Ce0.75Zr0.25O2催化剂中Ag的负载量对碳烟燃烧活性的影响

doi:10.11949/j.issn.0438-1157.20161683

化工学报 ›› 2017, Vol. 68 ›› Issue (8): 3064-3070.DOI: 10.11949/j.issn.0438-1157.20161683

• 催化、动力学与反应器 • 上一篇下一篇

Ag/Ce_0.75Zr_0.25O₂催化剂中Ag的负载量对碳烟燃烧活性的影响

邓湘玲, 叶松寿, 曹志凯, 张诺伟, 郑进保, 陈秉辉

厦门大学化学工程与生物工程系, 醇醚酯化工清洁生产国家工程实验室, 能源材料化学协同创新中心, 福建厦门 361005

收稿日期:2016-11-29 修回日期:2017-05-05 出版日期:2017-08-05 发布日期:2017-08-05
通讯作者: 郑进保
基金资助:
国家自然科学基金项目（21303140， 21673187）；中央高校基本科研业务费专项资金项目（20720170029）。

Effect of Ag loading on soot oxidation for Ag/Ce_0.75Zr_0.25O₂ catalysts

DENG Xiangling, YE Songshou, CAO Zhikai, ZHANG Nuowei, ZHENG Jinbao, CHEN Binghui

National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemical and Biochemical Engineering, Xiamen University, Xiamen 361005, Fujian, China

Received:2016-11-29 Revised:2017-05-05 Online:2017-08-05 Published:2017-08-05
Supported by:
supported by the National Natural Science Foundation of China(21303140, 21673187) and the Fundamental Research Funds for the Central Universities(20720170029).

摘要/Abstract

摘要：

开发低温下高催化活性的柴油机碳烟颗粒燃烧催化剂是当前环境催化领域的热点问题。利用共沉淀的方法制备了用于碳烟催化燃烧反应的Ag/Ce_0.75Zr_0.25O₂催化剂。活性评价结果表明，相对于Ce_0.75Zr_0.25O₂催化剂，Ag的引入可显著降低碳烟催化燃烧温度。而且，Ag的负载量存在一个最佳值。以XRD、in-situ XRD、BET、TPR等表征手段探究了该系列催化剂结构性质及其变化产生的影响。结果表明，Ag与Ce物种间的相互作用可显著降低催化剂（特别是CeO₂表面氧）的还原温度。该相互作用使Ag/Ce_0.75Zr_0.25O₂催化剂在一定温度下（>200℃）就表现出Ag⁺的性质。这些性质与该催化剂具有较高的碳烟氧化活性相关。而且，该催化剂也表现出良好的稳定性。

关键词: Ag, 催化剂, 碳烟燃烧, 氧化, 多相反应

Abstract:

It is still important to develop soot oxidation catalysts with excellent activity under low temperature. Ag/Ce_0.75Zr_0.25O₂ was synthesized via coprecipitation method for soot oxidation. Compared with the catalytic performance of Ce_0.75Zr_0.25O₂, the introduction of Ag can lead to the decrease of soot-ignition temperature. Moreover, there is an optimal Ag loading. Subsequently, several methods such as XRD, in-situ XRD, BET, TPR were used to characterize the physicochemical properties of Ag-based catalysts. The results showed that the introduction of Ag resulted in decreasing the reduction temperature of surface oxygen species, being due to the interaction of Ag and Ce. The interaction also brings about the occurrence of Ag⁺ nature. And the feature is linked with the outstanding activity of soot oxidation for Ag-based catalyst. Furthermore, the Ag-based catalyst possessed fairly good stability in soot oxidation.

Key words: sliver, catalyst, soot combustion, oxidation, multiphase reaction

中图分类号:

O643.36

邓湘玲, 叶松寿, 曹志凯, 张诺伟, 郑进保, 陈秉辉. Ag/Ce_0.75Zr_0.25O₂催化剂中Ag的负载量对碳烟燃烧活性的影响[J]. 化工学报, 2017, 68(8): 3064-3070.

DENG Xiangling, YE Songshou, CAO Zhikai, ZHANG Nuowei, ZHENG Jinbao, CHEN Binghui. Effect of Ag loading on soot oxidation for Ag/Ce_0.75Zr_0.25O₂ catalysts[J]. CIESC Journal, 2017, 68(8): 3064-3070.

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Ag/Ce_0.75Zr_0.25O₂催化剂中Ag的负载量对碳烟燃烧活性的影响

Effect of Ag loading on soot oxidation for Ag/Ce_0.75Zr_0.25O₂ catalysts

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