化工学报 ›› 2003, Vol. 54 ›› Issue (1): 131-134.

• 过程系统工程 • 上一篇    下一篇

多尺度作用的D4/APAEDMS本体共聚过程仿真

罗正鸿;詹晓力;陈丰秋;阳永荣   

  1. 浙江大学化学工程与生物工程学系
  • 出版日期:2003-01-25 发布日期:2003-01-25

MULTIDIMENSION BULK-COPOLYMERIZATION MODEL OF OCTAMETHYLCYCLOTETRASILOXANE AND AMINO-SILICONE MONOMER

LUO Zhenghong;ZHAN Xiaoli;CHEN Fengqiu;YANG Yongrong   

  • Online:2003-01-25 Published:2003-01-25

关键词:

氨取代基有机硅单体, 八甲基环四硅氧烷, 多“弯管”流动模型, 反应-扩散联合动力学

Abstract: For high viscosity bulk-copolymerization of octamethylcyclotetrasiloxane and amino-silicone monomer, a multisyphon flow physical model was established.Based on the free volume and chemical reaction kinetic theories, a new computational model was developed to simulate the multisyphon flow model. As to the new model, the united influence of reaction and diffusion was reviewed and analyzed. The new model was used to simulate bulk- copolymerization of octamethylcyclotetrasiloxane and amino-silicone monomer and agreed well with the results.

Key words:

氨取代基有机硅单体, 八甲基环四硅氧烷, 多“弯管”流动模型, 反应-扩散联合动力学