化工学报 ›› 2003, Vol. 54 ›› Issue (12): 1783-1786.

• 材料科学与工程 • 上一篇    下一篇

由偏铝酸钠直接制取高纯γ-Al2O3

高建峰;徐春彦;王建中;王久芬;庄源益   

  1. 华北工学院化工系,山西 太原030051;南开大学环境科学与工程系,天津 300071
  • 出版日期:2003-12-25 发布日期:2003-12-25

DIRECT PREPARATION OF HIGH PURE γ-ALUMINA FROM SODIUM ALUMINATE

GAO Jianfeng;XU Chunyan;WANG Jianzhong;WANG Jiufen;ZHUANG Yuanyi   

  • Online:2003-12-25 Published:2003-12-25

关键词:

脱钠剂, 超深度脱硅剂, 拟薄水铝石, SB粉, 比表面

Abstract: The purification of mother liquor containing sodium aluminate by using desilication agent and the preparation of high pure pseudo-boehmite and gamma alumina are reported. The sodium aluminate in the mother liquor coming from Shanxi Aluminium Plant is treated with home-made desilication agent, the ratios of SiO2/Al2O3 and Fe2O3/Al2O3 in treated-solution are below 0.01%. The pseudo-boehmite is obtained with buffer solution deposition in which ammonia gas acts as a circulating medium. The specific surface area of pseudo-boehime powder reaches up to 300m2•g-1 and pore volume reaches about 0.7ml•g-1.The content of sodium in pseudo-boehime is below 0.005% after treating the pseudo-boehime with a sodium removal agent.The quality of this product is comparable to the SB powder made in Germany.Gamma alumina with a larger specific surface area and pore volume is obtained by temperature programmed calcination of pseudo-boehmite.

Key words:

脱钠剂, 超深度脱硅剂, 拟薄水铝石, SB粉, 比表面