化工学报 ›› 2008, Vol. 59 ›› Issue (10): 2687-2691.

• 现代化工技术 • 上一篇    

红土镍矿有价元素高附加值利用的绿色冶金工艺(Ⅰ)熔融碱法提硅制备白炭黑

刘岩;张霞;申晓毅;翟玉春;徐冬   

  1. 东北大学材料与冶金学院
  • 出版日期:2008-10-05 发布日期:2008-10-05

Technology research on green metallurgy of high added value utilization of valuable elements in laterite nickel ore (Ⅰ) Preparation of silica white using molten NaOH extracting silicon method

LIU Yan; ZHANG Xia; SHEN Xiaoyi; ZHAI Yuchun; XU Dong   

  • Online:2008-10-05 Published:2008-10-05

摘要: 以红土镍矿为原料,采用碱熔融-碳酸化分解工艺制备出白炭黑产品。研究表明,SiO2的浸出率随反应时间、碱矿比的增加和红土镍矿粒度的减小而增加,随反应温度的升高而先增加后减少。经XRD分析,产品为无定型结构;经FT-IR检测产品为水合二氧化硅;经SEM检测产品颗粒均匀,粒度小于100nm。产品理化性能符合国家化工行业HG/T3065-1999标准。

关键词:

红土镍矿, 碱熔融, 白炭黑, 碳酸化分解

Abstract:

Silica white was prepared with the method of molten NaOHcarbonation decomposition from the laterite nickel ore, and the content of NiO in the residue reached 2.71%The results showed that the extraction ratio of SiO2 increased with increasing reaction time and mass ratio of alkali to ore, and with decreasing particle size of the laterite nickel oreFurthermore, the extraction ratio of SiO2 increased firstly and then decreased with increasing reaction temperatureXRD analysis indicated that the product was amorphousFT-IR analysis indicated that the product was hydrated silicon dioxideSEM morphology showed that the product was of uniform particle size with average particle size about 100 nmThe physical and chemical properties of the product conformed with the national standards of chemical industry.

Key words:

红土镍矿, 碱熔融, 白炭黑, 碳酸化分解