Liquid-solid Equilibria in Quinary System Na+, K+, Mg2+//Cl-, NO3--H2O at 25℃

CIESC Journal ›› 2011, Vol. 19 ›› Issue (1): 101-107.

Liquid-solid Equilibria in Quinary System Na⁺, K⁺, Mg²⁺//Cl^-, NO₃^--H₂O at 25℃

黄雪莉, 李松菀

College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

收稿日期:2010-07-08 修回日期:2010-10-15 出版日期:2011-02-28 发布日期:2011-02-28
通讯作者: HUANG Xueli, E-mail: xuelih@163.com
基金资助:
Supported by the National Natural Science Foundation of China(20466003,20866008)

Liquid-solid Equilibria in Quinary System Na⁺, K⁺, Mg²⁺//Cl^-, NO₃^--H₂O at 25℃

HUANG Xueli, LI Songwan

College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

Received:2010-07-08 Revised:2010-10-15 Online:2011-02-28 Published:2011-02-28
Supported by:
Supported by the National Natural Science Foundation of China(20466003,20866008)

摘要/Abstract

摘要： The solubilities of the quinary system Na⁺,K⁺,Mg²⁺//Cl,NO₃^--H₂O and its two quaternary subsystems, Na⁺,K⁺,Mg²⁺//NO₃^--H₂O and K⁺,Mg²⁺//Cl,NO₃^--H₂O,were studied by isothermal method at 25℃ and their phase diagrams were plotted.In the equilibrium phase diagram of quaternary system Na⁺,K⁺,Mg²⁺//NO₃^--H₂O, there are one invariant point,three univariant curves and three regions of crystallization with one salt:NaNO₃, KNO₃ and Mg(NO₃)2·6H₂O.In the equilibrium phase diagram of quaternary system K⁺,Mg²⁺//Cl,NO₃^--H₂O,there are three invariant points,seven univariant curves and five regions of crystallization with one salt:KNO₃,KCl, Mg(NO₃)2·6H₂O,MgCl₂·6H₂O and KCl·MgCl₂·6H₂O.In the equilibrium phase diagram of the quinary system Na⁺, K⁺,Mg²⁺//Cl,NO₃^--H₂O,there are four invariant points,and seven regions of crystallization with one salt:NaCl, KCl,NaNO₃,KCl·MgCl₂·6H₂O,KNO₃,MgCl₂·6H₂O and Mg(NO₃)2·6H₂O.

关键词: quinary system, phase equilibrium, nitrate, solubility

Abstract: The solubilities of the quinary system Na⁺,K⁺,Mg²⁺//Cl,NO₃^--H₂O and its two quaternary subsystems, Na⁺,K⁺,Mg²⁺//NO₃^--H₂O and K⁺,Mg²⁺//Cl,NO₃^--H₂O,were studied by isothermal method at 25℃ and their phase diagrams were plotted.In the equilibrium phase diagram of quaternary system Na⁺,K⁺,Mg²⁺//NO₃^--H₂O, there are one invariant point,three univariant curves and three regions of crystallization with one salt:NaNO₃, KNO₃ and Mg(NO₃)2·6H₂O.In the equilibrium phase diagram of quaternary system K⁺,Mg²⁺//Cl,NO₃^--H₂O,there are three invariant points,seven univariant curves and five regions of crystallization with one salt:KNO₃,KCl, Mg(NO₃)2·6H₂O,MgCl₂·6H₂O and KCl·MgCl₂·6H₂O.In the equilibrium phase diagram of the quinary system Na⁺, K⁺,Mg²⁺//Cl,NO₃^--H₂O,there are four invariant points,and seven regions of crystallization with one salt:NaCl, KCl,NaNO₃,KCl·MgCl₂·6H₂O,KNO₃,MgCl₂·6H₂O and Mg(NO₃)2·6H₂O.

Key words: quinary system, phase equilibrium, nitrate, solubility

黄雪莉, 李松菀. Liquid-solid Equilibria in Quinary System Na⁺, K⁺, Mg²⁺//Cl^-, NO₃^--H₂O at 25℃[J]. CIESC Journal, 2011, 19(1): 101-107.

HUANG Xueli, LI Songwan. Liquid-solid Equilibria in Quinary System Na⁺, K⁺, Mg²⁺//Cl^-, NO₃^--H₂O at 25℃[J]. , 2011, 19(1): 101-107.

参考文献

1 Su, Y.G., Lü, B.L., Wang, X.R., The Study on Phase Diagram of Inorganic Chemical Production (1) Theoretical Foundation, Chemical Industry Press, Beijing, 223-257(1985). (in Chinese)
2 Li, Y.W., Han, W.T., “Study on the liquid-solid equilibrium of the quinary system Na⁺, K⁺//Cl^-,SO₄^2-,NO₃^- -H₂O”, Chinese. Sci. Bulletin, 43 (19), 2089-2091 (1998). (in Chinese)
3 Huang, X.L., Lü, B.L., “Study on phase diagram of manufacture of KNO₃ from saltpeter (1)”, Inorg. Chem. ind., 28 (1), 9-11(2001). (in Chinese)
4 Huang, X.L., Gao, F., Hu, K.L., Minawaer, “Study on phase diagram of manufacture of KNO₃ from saltpeter (2)”, Inor. Salt Ind., 32 (5),37-40 (2001). (in Chinese)
5 Huang, X.L., “Advances of research and technology with nitrate in xinjiang Lop Nur”, Modern Chem. Ind., 26 (7), 10-12 (2006). (in Chinese)
6 Huang, X.L., Ma, F.Y., Hu, Z.Z., “Study on the preparation of KNO₃ from the brine”, Ind. Minerals & Processing, 62 (12), 1-4 (2002). (in Chinese)
7 Huang, X.L., Zhang, J.S., Hu, Z.Z., Ma, F.Y., “Study on preparation of KNO₃ from the brine in Xinjiang Lop Nur(2)”, Ind. Minerals & Processing, 33 (8), 6-7 (2004). (in Chinese)
8 Huang, X.L., Zhang, J.S., Hu, Z.Z., Ma, F.Y., “Study on preparation of KNO₃ from the brine in Xinjiang Lop Nur(3)”, Ind. Minerals & Processing, 33 (10), 13-15 (2004). (in Chinese)
9 Huang, X.L., Song, P.S., Chen, L.J., Lü, B.L., “Liquid-solid equilibria in quinary system Na⁺, Mg²⁺/Cl^-,SO₄^2-,NO₃^--H₂O at 298.15 K”, Calphad, 32 (1), 188-194 (2008).
10 Silcok., H., Solubililies of Inorganic and Organic Compounds, Pergamon Press, New York (1979).
11 Lü, B.L., “The correlation of activity coefficients for the electrolyte-nonelectrolyte mixed solution—The thermodynamics of the liquid solid phase equilibria in (NH₂)₂ CO-NaCl-NH₄Cl-H₂O system”, Acta Chimica Sinica, 44 (4), 283-293 (1986).
12 Analytical Room of Qinghai Institute of Salt-lake, Academia Sinica in China, The Analyses of Brines and Salts (China), Science Press, Beijing (1988).
13 Samant, K.D., Ng., Ka M., “Representation of high-dimensional solid-liquid phase diagrams of ionic systems”, AIChE, 47 (4), 861-879 (2001).

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Liquid-solid Equilibria in Quinary System Na⁺, K⁺, Mg²⁺//Cl^-, NO₃^--H₂O at 25℃

Liquid-solid Equilibria in Quinary System Na⁺, K⁺, Mg²⁺//Cl^-, NO₃^--H₂O at 25℃

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