化工学报 ›› 2012, Vol. 63 ›› Issue (S1): 199-203.DOI: 10.3969/j.issn.0438-1157.2012.z1.034

• 能源和环境工程 • 上一篇    下一篇

变负载工况下微生物燃料电池响应特性

李俊,张亮,朱恂,叶丁丁,廖强   

  1. 重庆大学工程热物理研究所,低品位能源利用技术及系统教育部重点实验室,重庆 400030
  • 收稿日期:2012-03-20 修回日期:2012-03-26 出版日期:2012-05-28 发布日期:2012-05-28
  • 通讯作者: 李俊
  • 基金资助:

    具有可再生阴极的碱性微生物燃料电池内多场驱动的多组分物质传输特性研究;微生物能源转化过程中的多尺度热物理问题研究;微生物降解有机废物与产能综合利用过程中生物膜成膜特性及传输特性研究;核蒸汽传热管应力腐蚀开裂的电化学噪声;教育部新世纪人才资助计划

Response of a microbial fuel cell to variable loads

LI Jun,ZHANG Liang,ZHU Xun,YE Dingding,LIAO Qiang   

  • Received:2012-03-20 Revised:2012-03-26 Online:2012-05-28 Published:2012-05-28
  • Contact: Jun Li LI

摘要: 变工况运行时微生物燃料电池(MFC)的响应特性是揭示其运行规律的重要因素之一,对于指导MFC的实际应用有重要意义。分别针对以50、100、400和1000Ω启动的双室型MFC,以电池的电压响应和性能参数为评价指标,研究了MFC的启动特性和启动完成后MFC对负载变化的响应特性。结果表明,启动电阻越小电池启动越慢,但其最大功率密度越大。与MFC-50和MFC-100相比,MFC-1000和MFC-400对50Ω负载响应的时间较长,且其负载电压均表现出先急剧下降后缓慢上升的特征。经过较长时间的适应期后,所有电池的最大功率密度均可达到2000 mW·m-2以上。此后,当上述MFC的负载切换为原培养电阻时,其响应时间明显缩短且电池最高功率密度不再发生变化。

关键词: 变负载, 性能响应, 微生物燃料电池, 质子传输

Abstract: Response of a microbial fuel cell under variable load conditions is of paramount importance when it is used for the application of wastewater treatment.In this study,four two-chamber MFCs were started up and evaluated under an external resistance of 50,100,400,1000 Ω,respectively.The results indicated that MFC-50 has the longest log phase for the development of the biofilm while a highest maximum power density can be obtained after start-up.It was also found that the voltages of MFC-100 and MFC-50 dropped and maintained a steady-state when a 50Ω resistance was connected into the electrical circuit,whereas the voltages of MFC-400 and MFC-1000 elevated slowly for ~2 d to the values similar to those of MFC-200 and MFC-50 after the initial abrupt drop under the same loading condition.After the stabilization of the MFCs,the maximum power densities of all the MFCs were comparable and reached 2000 mW·m-2.Further switching the external resistance from a small to large one,no noticeable change in performance can be found.

Key words: variable load, performance response, microbial fuel cells, proton transfer

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