基于冠醚的离子识别响应型智能材料研究新进展

doi:10.3969/j.issn.0438-1157.2013.01.028

化工学报 ›› 2013, Vol. 64 ›› Issue (1): 261-267.DOI: 10.3969/j.issn.0438-1157.2013.01.028

基于冠醚的离子识别响应型智能材料研究新进展

巨晓洁, 谢锐, 汪伟, 褚良银

四川大学化学工程学院,四川成都 610065

收稿日期:2012-08-06 修回日期:2012-09-18 出版日期:2013-01-05 发布日期:2013-01-05
通讯作者: 褚良银
作者简介:巨晓洁(1980—),女,博士,副教授。
基金资助:
国家重点基础研究发展计划项目(2009CB623407);国家自然科学基金项目(20906064);全国优秀博士学位论文作者专项资金资助项目(201163)。

Development of ion-recognition-responsive smart materials based on crown ethers

JU Xiaojie, XIE Rui, WANG Wei, CHU Liangyin

School of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China

Received:2012-08-06 Revised:2012-09-18 Online:2013-01-05 Published:2013-01-05
Supported by:
supported by the National Basic Research Program of China (2009CB623407),the National Natural Science Foundation of China (20906064) and the Foundation for the Author of National Excellent Doctoral Dissertation of China (201163).

摘要/Abstract

摘要： 金属离子对生物体的生命活动起着核心的作用,而一些重金属离子(如Pb²⁺、Hg²⁺)在很低浓度时就对生物具有极强的毒性;因此,研究具有金属离子识别特性的智能材料具有重要的理论价值和实用意义。冠醚具有选择性地络合金属离子的能力,研究者们将冠醚的离子识别特性与聚(N-异丙基丙烯酰胺)的相变行为特性相结合制备了一系列离子识别响应型智能材料。综述了近年来基于18-冠-6和15-冠-5两种冠醚分子的离子识别响应型智能材料的研究新进展。目前,基于冠醚的离子识别响应型智能材料仍多处于基础研究阶段,还需要进一步系统深入研究和开发完善。

关键词: 智能材料, 离子识别, 响应特性

Abstract: Metal ions play an important role in life activities, but some heavy metal ions (such as Pb²⁺ and Hg²⁺) have high toxicity to the organisms even at alow concentration.It is of important theoretical significance and great practical interest to study smart materials with metal ion-recognition properties. Crown ethers have remarkable recognition ability towards specific mental ions.A series of ion-recognition-responsive smart materials composed of crown ethers and responsive poly (N-isopropylacrylamide) (PNIPAM) polymer have been developed.The development of ion-recognition-responsive smart materials based on 18-crown-6 and 15-crown-5 is reviewed.At present, the ion-recognition-responsive smart materials are still at the basic research stage and need further intensive study and development.

Key words: smart materials, ion-recognition, responsive property

中图分类号:

TQ317

巨晓洁, 谢锐, 汪伟, 褚良银. 基于冠醚的离子识别响应型智能材料研究新进展[J]. 化工学报, 2013, 64(1): 261-267.

JU Xiaojie, XIE Rui, WANG Wei, CHU Liangyin. Development of ion-recognition-responsive smart materials based on crown ethers[J]. CIESC Journal, 2013, 64(1): 261-267.

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基于冠醚的离子识别响应型智能材料研究新进展

Development of ion-recognition-responsive smart materials based on crown ethers

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