化工学报 ›› 2013, Vol. 64 ›› Issue (6): 2291-2299.DOI: 10.3969/j.issn.0438-1157.2013.06.052

• 材料化学工程与纳米技术 • 上一篇    下一篇

改性纳米SiO2/聚氨酯-含氟丙烯酸酯无皂乳液合成及其胶膜性能表征

周威, 傅和青, 颜财彬, 陈焕钦   

  1. 华南理工大学化学与化工学院,广东 广州 510640
  • 收稿日期:2012-11-12 修回日期:2012-12-29 出版日期:2013-06-05 发布日期:2013-06-05
  • 通讯作者: 傅和青
  • 作者简介:周威(1987—),男,硕士研究生。
  • 基金资助:

    国家自然科学基金项目(21171058)。

Synthesis and characterization of self-emulsified nano-SiO2/polyurethane-fluorinated polyacrylate hybrid latexes and their films

ZHOU Wei, FU Heqing, YAN Caibin, CHEN Huanqin   

  1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
  • Received:2012-11-12 Revised:2012-12-29 Online:2013-06-05 Published:2013-06-05
  • Supported by:

    supported by the National Natural Science Foundation of China(21171058).

关键词: 聚氨酯, 纳米SiO2, 含氟丙烯酸酯, 核壳结构, 无皂乳液

Abstract: SiO2/polyurethane (SiO2/PUL) latexes modified by nano-SiO2 (treated with γ-amino propyltriethoxy silane (KH550)) and end capped by hydroxyethyl methacrylate (HEMA) were first prepared through the prepolymer process.Then a series of nano-SiO2/polyurethane-fluorinated polyacrylate (SiO2/PUFA) hybrid latexes were synthesized via the seed emulsion polymerization process using hexafluorobutyl methacrylate (HFMA) as modifier, SiO2/PUL as macromolecule emulsifier and seed emulsion.The properties of nano-SiO2/PUFA emulsions and their films were characterized by Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), contact angle (CA),differential scanning calorimetry (DSC), thermogravimetry (TG) and tensile test machine.FT-IR characterization demonstrated that the polyurethane (PU) was successfully modified by modified nano-SiO2 and HFMA.TEM result indicated that the nano-SiO2 treated with KH550 was well dispersed in ethanol.Particle morphology of hybrid latex showed inverse core-shell structure, in which the core region was formed by acrylate (PA), while the shell region was formed by PU.TG result showed that the thermal stability of the latexes film was obviously improved by nano-SiO2 particles.Water resistance and mechanical properties of nano-SiO2/PUFA films were greatly improved due to the multiple cross-linking formed by modified nona-SiO2 and fluorinated acrylate through the chemical bonds with polyurethane chains.

Key words: polyurethane, nano-SiO2, fluorinated acrylate, core-shell structure, emulsifier-free emulsion

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