关键词:

重整化群理论, Stockmayer势能函数, 临界现象, 水

Abstract: The renormalization group theory is applied to calculating the critical behavior of water in which density fluctuation is taken into account.The Stockmayer potential is adopted to express the interactions between water molecules. The parameters regressed from critical temperature are used to predict the behavior of water at supercritical and near-critical temperatures. The calculated pressures are compared with the experiment data. The results show that the RG theory is suitable to predict the thermodynamic properties of water in critical region.

Key words:

重整化群理论, Stockmayer势能函数, 临界现象, 水