CIESC Journal ›› 2013, Vol. 64 ›› Issue (5): 1884-1889.DOI: 10.3969/j.issn.0438-1157.2013.05.052

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Solvent free synthesis of methyl dihydroxyethyl allyl ammonium chloride

MAO Taoyan1, ZHENG Cheng2, LIN Jing2, CHEN Xiaoling2, HUANG Xiaoluo2, XING Xu2, ZHANG Liping3   

  1. 1. School of Chemistry & Chemical Engineering, Guangxi University, Nanning 530004, Guangxi, China;
    2. Fine Chemicals Research institute, Guangzhou University, Guangzhou 510006, Guangdong, China;
    3. Guangzhou Tianci Silicone Technology Co. Ltd., Guangzhou 510660, Guangdong, China
  • Received:2012-08-28 Revised:2012-12-25 Online:2013-05-05 Published:2013-05-05

无溶剂合成甲基二羟乙基烯丙基氯化铵

毛桃嫣1, 郑成2, 林2, 陈晓玲2, 黄晓罗2, 邢旭2, 张利萍3   

  1. 1. 广西大学化学化工学院, 广西 南宁 530004;
    2. 广州大学精细化工研究所, 广东 广州 510006;
    3. 广州天赐有机硅科技有限公司, 广东 广州 510660
  • 通讯作者: 郑成
  • 作者简介:毛桃嫣(1986-),女,博士研究生。
  • 基金资助:

    广东省部产学研项目(20120980);广州市教育局科技项目穗教科[2013]26号;国家级大学生创新训练项目(201211078006)。

Abstract: Methyl dihydroxyethyl allyl ammonium chloride(MDAAC)was synthesized from N-methyl diethanolamine( MDEA )and allyl chloride by the solvent-free synthesis method.The effects of reaction time, reaction temperature and reactant molar ratio on reaction conversion rate were studied.The optimum process of synthesizing MDAAC obtained by orthogonal experiment was 60 min reaction time, 50℃ reaction temperature and 1∶1.3 molar ratio of MDEA and allyl chloride.The target product was purified by recrystallization and the yield of product was 97%.The structure of product was characterized by IR,1H NMR and 13C NMR.

Key words: solvent-free synthesis, methyl dihydroxyethyl allyl ammonium chloride, N-methyl diethanolamine

关键词: 无溶剂合成, 甲基二羟乙基烯丙基氯化铵, N-甲基二乙醇胺

CLC Number: