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Reactivity of Char in Gasification with Steam and Carbon Dioxide at High Temperatures

Tong Chuliang Yusaku Sakata and Shigeaki Kasaoka Lintong Fertilizer Industry Institute, Shanxi School of Engineering, Okayama University, Japan   

  • Online:1984-09-25 Published:1984-09-25

煤的水蒸汽及二氧化碳高温气化活性评价

童楚良,阪田祜作,笠岡成光   

  1. 临潼化肥工业研究所 ,日本冈山大学工学部合成化学科 ,日本冈山大学工学部合成化学科

Abstract: The reactivities of chars were investigated for gasification with steam and carbon dioxide by thermogravimetry in the temperature range of 1100 to 1400℃ and at atmospheric pressure, and the results were compared to those of the previous work at temperatures below 1000℃, where the gasification velocity was chemically controlled. The parent coals of the six char samples differed in rank from brown coal to anthracite and from non-caking coal to strongly caking coal. The rate equation, f=1- exp( -aθb), designated as the modified volume reaction model, was applied to evaluating gasification reactivities using an average rate constant k.

摘要: 选用燃料比(固定碳/挥发份)1到8,变质程度从褐煤到无烟煤(包括粘结性的和非粘结性的)的六种煤焦为试样,在1100—1400℃下,用热重量法进行了含O_2、H_2O、CO_2气化剂的实验室气化,用修正体积反应模型式进行了数据处理和活性评价.并将高温区的结果与低温区(1000℃以下)的实验结果进行了比较.