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XU Zhenlin; WANG Shaokun; TIAN Weimin; SHI Jun
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徐振林; 汪绍昆; 田维民; 时钧
Nanjing Institute of Chemical Technology
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Abstract: It is found that the expression for(γ/x)_x-o derived on the basis of Lenoir’s works should Ix differentfrom that derived by Kikic and Renon in 1976.and(lnγ_1,/x_1)_x_1=0 values have beenmeasured for 10 binary systems by gas-liquid chromatography.According to the new expression,UNIQUACparameters and the vapor-liquid eqilibrium data are evaluated.Of the six systems data available in litera-ture the predicted results are satisfactory.
摘要： It is found that the expression for(γ/x)_x-o derived on the basis of Lenoir’s works should Ix differentfrom that derived by Kikic and Renon in 1976.and(lnγ_1,/x_1)_x_1=0 values have beenmeasured for 10 binary systems by gas-liquid chromatography.According to the new expression,UNIQUACparameters and the vapor-liquid eqilibrium data are evaluated.Of the six systems data available in litera-ture the predicted results are satisfactory.
XU Zhenlin, WANG Shaokun, TIAN Weimin, SHI Jun. MEASUREMENT OF EXCESS GIBBS FREE ENERGY MODEL PARAMETERS BY CHROMATOGRAPHIC SLOPE METHOD[J]. .
徐振林, 汪绍昆, 田维民, 时钧. MEASUREMENT OF EXCESS GIBBS FREE ENERGY MODEL PARAMETERS BY CHROMATOGRAPHIC SLOPE METHOD[J]. CIESC Journal.
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