Abstract: The global kinetics of methanol synthesis from carbon monoxide, carbon dioxide and hydrogen under typical commercial conditions over C301 commercial Cu-based catalyst are studied in a CSTR. The two independent reactions in this work are chosen as follows: CO2 + 3H2 CH3OH + H2O Global kinetics model which conveniently describes the results is derived from the two reactions. The influence of reaction conditions on the effectiveness factor of methanol synthesis is also discussed.

摘要： 本文以工业应用为目的,采用内循环无梯度反应器,在工业甲醇合成操作条件下研究了工业粒度C301型铜基催化剂上一氧化碳、二氧化碳与氢合成甲醇的宏观动力学.选择以下二个反应:CO+2H_2(?)CH_3OH CO_2+3H_2(?)CH_3OH+H_2O为系统的独立反应,获得了可供实用的宏观动力学方程,并讨论了反应条件对甲醇合成效率因子的影响.