• 化工学报 • Previous Articles     Next Articles

Sorption Model of Pure Gases in Amorphous Polymers(Ⅱ) Applicatons

Zeng Zuoxiang and Xue WeiSan Wang Shaoting (East China Institute of Chemical Technology, Shanghai 200237) (Department of Chemical Engineering, Tianjin University, Tianjin 300072)   

  • Online:1992-02-25 Published:1992-02-25

纯气体在非晶态高分子膜内的吸收机理模型(Ⅱ)应用

曾作祥,薛为岚,王绍亭   

  1. 华东化工学院化工研究所,华东化工学院化工研究所,天津大学化工系 上海200237 ,上海200237 ,天津300072

Abstract: This paper describes an apparatus for measuring both pure and mixed gas sorption in amorphous polymers. Sorption data were reported for pure gases (CO2, CH4, C2H4 and C2H6) in three amorphous polymers[poly(methal methacry-lateXPMMA), pplyimde(PI) and poly(vinyl acetate) (PVA)]. These results and some data reported in literature show that the sorption model developed in Part I of this series can be applied to amorphous polymers both above and below the glass-transition temperature and that the model parameters can be correlated with the molecular properties and characteristics of the polymers and penetrant.

摘要: 对CO_2、CH_4、C_2H_4和C_2H_6等4种纯气体进行了吸收等温线的测试,通过数据表明在(Ⅰ)报中提出的吸收机理模型是普遍适用的,模型参数也能较好地与高分子和渗透分子的物性数据关联.