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Interface-Reaction Model for Solid-Liquid Reactions——Hydrolysis of Phthalic Anhydride

Wang Changtai, Lin Cheng, Chen Zhengyu and Liu Guozhong (Fuzhou University, Fuzhou, 350002)   

  • Online:1992-02-25 Published:1992-02-25

固液反应的界面反应模型——中速苯酐水解反应

王长泰,林诚,陈征宇,刘国忠   

  1. 福州大学化工系,福州大学化工系,福州大学化工系,福州大学化工系 福州350002 ,福州350002 ,福州350002 ,福州350002

Abstract: The Interface-Reaction model proposed by the authors earlier for solid-liquid reactions was success fully applied to a typical moderate rate reaction, the hydrolysis of phthalic anhydride in aqueous solution of NaOH. This success in simulating non-instantaneous reaction strongly manifests the capability of the model in describing the behavior of some solid-liquid reactions. The jD factor for mass transfer in the reaction system equipped with flat-blade turbine agitator was found to increase with increasing Re for the first time, and the necessity of inclusion of Scm on the right hand side of jD-Re equations was also found in this work.

摘要: 应用作者提出的固液反应新模型——界面反应模型分析处理典型的中速反应苯酐在碱水溶液中的水解反应,并获成功.这一形式简单、使用极方便的数学模型在非瞬间反应系统的成功应用,更有力地证明其对某些类固液反应的适用性.本文并发现平桨搅拌系统j_D~R_e函数关系的特殊性以及在j_D~R_e函数式中添加尼Sc~m项的必要性.