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MACROPROCESS OF PARTICLE FORMATION IN SUSPENSION POLYMERIZATION OF STYRENE WITH INORGANIC STABILIZER SYSTEM

FANG Shijiang; PAN Renyun; ZHOU Qiyun; TANG Shunying; YUAN Huigen   

  1. Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:1991-10-18 Revised:1992-05-13 Online:1993-03-28 Published:1993-03-28
  • Contact: FANG Shijiang

MACROPROCESS OF PARTICLE FORMATION IN SUSPENSION POLYMERIZATION OF STYRENE WITH INORGANIC STABILIZER SYSTEM

方仕江; 潘仁云; 周其云; 唐舜英; 袁惠根   

  1. Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, China
  • 通讯作者: 方仕江

Abstract: The macroprocess of particle formation from suspension droplets of styrene in a pdymerizationsystem was investigated.Inorganic hydroxyapatite or its mixture with polyvinyl alcohol as thepolymerization system was used.Those items such as the effects of the Weight fraction of dispersed-phase,the amount of the inorganic stabilizer and the agitation speed on the breakup and coalescence of thetransient dispersed drops etc.Were examined.Results showd that the dynamic behavior of the transi-ent polymer droplets changed in the presence of the suspension stabilizer during the reaction.

Key words: styrene, suspension polymerization, inorganic stabilizer, drop size and drop size distribution, breakup and coalescence

摘要: The macroprocess of particle formation from suspension droplets of styrene in a pdymerizationsystem was investigated.Inorganic hydroxyapatite or its mixture with polyvinyl alcohol as thepolymerization system was used.Those items such as the effects of the Weight fraction of dispersed-phase,the amount of the inorganic stabilizer and the agitation speed on the breakup and coalescence of thetransient dispersed drops etc.Were examined.Results showd that the dynamic behavior of the transi-ent polymer droplets changed in the presence of the suspension stabilizer during the reaction.

关键词: styrene;suspension polymerization;inorganic stabilizer;drop size and drop size distribution;breakup and coalescence