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SURFACE FRACTALITY STRUCTURE OF γ -Al_2O_3

Ge Qingfeng, Li Shaofen and Liao Hui (Department of Chemical Engineering Tianjin University, Tianjin 300072)   

  • Online:1993-04-25 Published:1993-04-25

γ-氧化铝的表面分形结构

葛庆峰,李绍芬,廖晖   

  1. 天津大学化学工程系,天津大学化学工程系,天津大学化学工程系 天津300072 ,天津300072 ,天津300072

Abstract: The surface pore structure of porous γ-A12O3 was investigated with SEM and adsorption methods. The SEM photos with different magnifications showed that the surface of γ - A12O3 particle was of self-similarity qualitatively. The monolayer values of different ad-sorbates were determined with the frontal gas chromatography. The surface pore structure was analyzed on the basis of fractal geometry and a fractal dimension of 2. 78 was calculated from the experimental data.

摘要: 在多相催化反应过程中,化学反应与多孔催化剂的表面密切相关。由于表面的不规则性, 以往基于欧氏几何的数学处理,显得过于理想化和简单化。近年来发展起来的分形几何为更 好地表征催化剂及载体的表面拓朴特征提供了新的可能。在这方面,Avnir、Pfeifer和Farm 等f‘-引做了一系列的工作,认为自然界中许多物质属干表面分形,其分形维数为2~人