SOLUBILITY OF SOLID SULFUR IN SUPER / NEAR -CRITICAL H_2S-CONTAINING SOUR FLUID MIXTURES(I) EXPERIMENTAL INVESTIGATION

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SOLUBILITY OF SOLID SULFUR IN SUPER / NEAR -CRITICAL H_2S-CONTAINING SOUR FLUID MIXTURES(I) EXPERIMENTAL INVESTIGATION

Gu Mingxing, Li Qun, Zhou Xiangyang, Chen Weidong and Guo Tianmin (University of Petroleum, Department of Chemical Engineering, Beijing 100083)

Online:1993-06-25 Published:1993-06-25

固体硫在超临界/近临界酸性流体中的溶解度(Ⅰ)实验研究

谷明星,里群,邹向阳,陈卫东,郭天民

石油大学化工系,石油大学化工系,石油大学化工系,石油大学化工系,石油大学化工系北京100083.中国寰球化学工程公司 ,北京100083 ,北京100083 ,北京100083 ,北京100083

Abstract

Abstract: In this paper a high-pressure equilibrium device was developed for measuring the solubility of solids or liquids in supercritical fluids by the static method. The solubility data of solid sulfur in super / near-critical H2S, CO2, CH4 and H2S-rich sour fluid mixtures were measured respectively. Some of the data are published for the first time. The agreement of the experimental results with the data from the literature shows the reliability of the developed device and method.

摘要： 建立了1套静态法测定难挥发物质(固体或液体)在超临界/近临界流体中溶解度的实验装置,并测定了固体硫在近临界硫化氢、超临界CO_2、CH_4及富硫化氢酸性气体混合物中的溶解度数据,取得了较好的结果.

Gu Mingxing, Li Qun, Zhou Xiangyang, Chen Weidong and Guo Tianmin (University of Petroleum, Department of Chemical Engineering, Beijing 100083). SOLUBILITY OF SOLID SULFUR IN SUPER / NEAR -CRITICAL H_2S-CONTAINING SOUR FLUID MIXTURES(I) EXPERIMENTAL INVESTIGATION[J]. .

谷明星,里群,邹向阳,陈卫东,郭天民. 固体硫在超临界/近临界酸性流体中的溶解度(Ⅰ)实验研究 [J]. CIESC Journal.