PREDICTION EQUATION OF CONDUCTANCEFOR DILUTE ELECTROLYTE SOLUTIONS

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PREDICTION EQUATION OF CONDUCTANCEFOR DILUTE ELECTROLYTE SOLUTIONS

Ni Liang,Jiang Wenhua and Han Shijun(Department of Chemistry,Zhejiang University,Hangzhou 310027)

Online:2000-04-25 Published:2000-04-25

强电解质稀溶液电导的预测方程

倪良,蒋文华,韩世钧

浙江大学化学系!杭州310027,浙江大学化学系!杭州310027,浙江大学化学系!杭州310027

Abstract

Abstract: Based on Onsager and Onsager-Fuoss-Chen equations of conductance,a new prediction equation is proposed for dilute electrolyte solution. It is used to predict and calculate the conductance of some single strong electrolyte solutions and their mixtures at 298.15 K. The results show good agreements with those data from literatureand they are better than those calculated with Onsager limiting equation and two-parameter Onsager-Fuoss-Chen equation. In addition,the new equation can also be used to determine the limiting molar conductivityof strong electrolyte by one-point experimental data of the molar conductivityat a certain concentration.The calculation deviation of the new equation shows a minimum value when the strength of ion in solution approaches 0.001 mol·dm~-3,hence,so long as the molar conductivity near this point is measured,the limitingmolar conductivity can be calculated conveniently and reliably by the new equation.

CLC Number:

O646.1

Ni Liang,Jiang Wenhua and Han Shijun(Department of Chemistry,Zhejiang University,Hangzhou 310027). PREDICTION EQUATION OF CONDUCTANCEFOR DILUTE ELECTROLYTE SOLUTIONS[J]. .

倪良,蒋文华,韩世钧. 强电解质稀溶液电导的预测方程 [J]. CIESC Journal.

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