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Isothermal and Isobaric Vapor-Liquid Equilibria of α-Pinene+cis-Pinane+1-Hexanol
System

MA Lu; LI Haoran; WANG Congmin; HAN Shijun   

  1. Department of Chemistry, Zhejiang University, Hangzhou 310027, China
  • Received:1900-01-01 Revised:1900-01-01 Online:2004-02-28 Published:2004-02-28
  • Contact: MA Lu

α-蒎烯+顺式蒎烷+正已醇体系的等温等压汽液平衡

马璐; 李浩然; 王从敏; 韩世钧   

  1. Department of Chemistry, Zhejiang University, Hangzhou 310027, China
  • 通讯作者: 马璐

Abstract: This paper presents the isothermal and isobaric vapor-liquid equilibria measured with an
inclined ebulliometer for α-pinene + cis-pinane + 1-hexanol system at temperatures of
368.15K, 383.15 K and 408.15K, and at pressures of 26.66 kPa and 53.33 kPa. The measured
ternary results are analyzed using the UNIQUAC equation with the temperature-dependent
binary parameters. Satisfactory agreements are obtained between the experimental results
and the theoretical analysis.

Key words: Antoine equation, ebulliometer, Powell optimization, UNIQUAC

摘要: This paper presents the isothermal and isobaric vapor-liquid equilibria measured with an
inclined ebulliometer for α-pinene + cis-pinane + 1-hexanol system at temperatures of
368.15K, 383.15 K and 408.15K, and at pressures of 26.66 kPa and 53.33 kPa. The measured
ternary results are analyzed using the UNIQUAC equation with the temperature-dependent
binary parameters. Satisfactory agreements are obtained between the experimental results
and the theoretical analysis.

关键词: Antoine equation;ebulliometer;Powell optimization;UNIQUAC