Iron Arene Salts as Initiators for Thermal Curing of Epoxides by Photo-catalysis

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Iron Arene Salts as Initiators for Thermal Curing of Epoxides by Photo-catalysis

WANG Tao; LI Baoshan; YU Meng; WAN Pinyu

DepartmentofChemistry,BeijingUniversityofChemicalTechnology,Beijing100029,China

Received:1900-01-01 Revised:1900-01-01 Online:2005-04-28 Published:2005-04-28
Contact: WANG Tao

光催化芳茂铁盐作为热引发剂引发环氧化合物固化

王涛; 李保山; 于萌; 万平玉

DepartmentofChemistry,BeijingUniversityofChemicalTechnology,Beijing100029,China

通讯作者: 王涛

Abstract

Abstract: [Cyclopentadien-Fe-naphthalene]BF4(CFN) and [cyclopentadien-Fe-anisole]BF4(CFA) thermal cationic initiators for the curing of epoxide E44 and GGE were investigated. CFN brought out the curing of E44 at 89.1℃ and that of GGE at 148.7℃. However, CFA had much less thermal initiating activity under 300℃. Under UV radiation for short time, the thermal initiating activities of CFN and CFA were enhanced obviously. It was observed that the initiating onset temperature decreased and the evolved heat of the curing increased. Both CFN and CFA can carrv out the polvmerization of E44 and GGE near 85℃ and 112℃ by UV radiation.

Key words: thermal initiators, photo-catalyses, epoxide

摘要： [Cyclopentadien-Fe-naphthalene]BF4(CFN) and [cyclopentadien-Fe-anisole]BF4(CFA) thermal cationic initiators for the curing of epoxide E44 and GGE were investigated. CFN brought out the curing of E44 at 89.1℃ and that of GGE at 148.7℃. However, CFA had much less thermal initiating activity under 300℃. Under UV radiation for short time, the thermal initiating activities of CFN and CFA were enhanced obviously. It was observed that the initiating onset temperature decreased and the evolved heat of the curing increased. Both CFN and CFA can carrv out the polvmerization of E44 and GGE near 85℃ and 112℃ by UV radiation.

关键词: 铁有机化合物;热加工技术;环氧化物;光学催化剂

WANG Tao, LI Baoshan, YU Meng, WAN Pinyu. Iron Arene Salts as Initiators for Thermal Curing of Epoxides by Photo-catalysis[J]. .

王涛,李保山,于萌,万平玉. 光催化芳茂铁盐作为热引发剂引发环氧化合物固化[J]. CIESC Journal.

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