CIESC Journal ›› 2005, Vol. 56 ›› Issue (10): 2004-2008.
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CHU Mo;ZHU Shuquan;LI Huamin;HUANG Zhanbin;ZOU Lizhuang
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初茉;朱书全;李华民;黄占斌;邹力壮
Abstract: A composite superabsorbent resin(HA-PAA) for agricultural application was prepared by the surface cross-linking reaction of sulfonated humic acid and poly acrylic acid.N,N′-methylenebisacryamide dissolved in methanol solution was used as surface cross-linking agent.The effect of the ratio of sulfonated humic to poly acrylic acid, the concentration of cross-linking agent, and volume ratio of methanol to deionized water on water absorbency was investigated.In contrast with poly acrylic acid, the surface structure of HA-PAA was analyzed by microscopic investigation, and water-absorbing mechanism was explored.The experimental results showed that HA-PAA with 10%(mass) humic acid possessed better water absorbency and electrolyte resistance.Compared with the sample of poly acrylic acid, the water retention of HA-PAA in sand was also studied.The water retention of the sand was enhanced greatly when mixed with 0.2% HA-PAA.HA-PAA can be used as water-managing and growth-improving materials for agriculture and horticulture purposes in desert-prone areas.
Key words: 磺化腐殖酸, 聚丙烯酸, 表面交联, 土壤保水性, 高吸水性树脂
摘要: 将交联剂N,N′-亚甲基双丙烯酰胺溶于甲醇溶液制成表面处理液,通过表面交联反应将磺化腐殖酸(HA)与聚丙烯酸(PAA)结合,制得一种适合于农林领域应用的腐殖酸-聚丙烯酸高吸水性树脂(HA-PAA).研究了表面处理液浓度、交联剂用量和腐殖酸量对HA-PAA吸水性能的影响规律和吸水机理,以及产物在沙土中的保水性能,并通过扫描电镜分析了HA-PAA的表面结构.研究结果表明,当含有10% HA时,HA-PAA耐电解质性能良好,吸水性能最佳;当沙土中添加0.2%的HA-PAA时,可明显改善沙土的贮水、保水性能.HA-PAA作为农林领域用保水剂,可发挥抗旱保墒和促进植物生长的双重作用.
关键词: 磺化腐殖酸, 聚丙烯酸, 表面交联, 土壤保水性, 高吸水性树脂
CHU Mo, ZHU Shuquan, LI Huamin, HUANG Zhanbin, ZOU Lizhuang. Synthesis and characterization of surface cross-linked humic acid/poly acrylic acid superabsorbent resin[J]. CIESC Journal, 2005, 56(10): 2004-2008.
初茉, 朱书全, 李华民, 黄占斌, 邹力壮. 腐殖酸-聚丙烯酸表面交联吸水性树脂的合成与性能 [J]. 化工学报, 2005, 56(10): 2004-2008.
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