CIESC Journal ›› 2005, Vol. 56 ›› Issue (9): 1690-1693.
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ZHAO Wei;LI Zengxi;ZHANG Suojiang;PANG Haijian;DONG Haifeng;ZHANG Xiangping
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赵威;李增喜;张锁江;庞海舰;董海峰;张香平
Abstract: Supported multi-metal catalyst was prepared by impregnation.A variety of factors such as reaction temperature, feedstock ratio, alkali concentration, catalyst concentration and antipolymerizer concentration were systematically investigated in terms of their effects on the oxidative esterification reaction for methyl methacrylate production from methacrolein.The experimental results showed that under the condition of temperature 333 K,methanol/methacrolein ratio 97∶1(molar ratio),NaOH concentration 0.001 g8226;ml-1 and catalyst concentration 0.02 g8226;ml-1, methacrolein conversion and methyl methacrylate selectivity were about 100% and 71.4% respectively, after 30 min reaction.
Key words: 甲基丙烯醛, 甲基丙烯酸甲酯, 氧化, 酯化, 催化反应
关键词: 甲基丙烯醛, 甲基丙烯酸甲酯, 氧化, 酯化, 催化反应
ZHAO Wei, LI Zengxi, ZHANG Suojiang, PANG Haijian, DONG Haifeng, ZHANG Xiangping. Oxidative esterification of methacrolein to methyl methacrylate[J]. CIESC Journal, 2005, 56(9): 1690-1693.
赵威, 李增喜, 张锁江, 庞海舰, 董海峰, 张香平. 甲基丙烯醛氧化酯化制备甲基丙烯酸甲酯 [J]. 化工学报, 2005, 56(9): 1690-1693.
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