Research of linking process of alginate with divalent ions by circular dichroism
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LI Hongbing
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李红兵
天津大学化工学院,天津 300072
Abstract: The steadystate interaction research of calcium and zinc ions with alginate during the sol-gel transition by circular dichroism showed that this process included two phases.During the first phase before the transition point the structure of the gel-conjugate of alginate-metal ions was homological in the range of linear change.The rate and mechanism have the similar change.Molar ellipticity [θ]alginateCa at wavelength 200 nm and 205 nm,molar ellipticity [θ]alginateZn at wavelength 195 nm and 200 nm could be obtained through calculation with spectrum titration.For the same divalent cation ion,the critical sol-gel transition points were different for alginates with different compositions.
LI Hongbing.
李红兵 . 海藻酸钠离子交换过程的圆二色谱 [J]. CIESC Journal.
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https://hgxb.cip.com.cn/EN/Y2006/V57/I10/2497