CIESC Journal ›› 2006, Vol. 57 ›› Issue (7): 1709-1714.
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GUO Jintang;LIN Fangqian;LIU Bing;ZHAO Meihua
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郭锦棠;林芳茜;刘冰;赵美华
Abstract: Polycarbonate urethane was synthesized from polycarbonate diol(PCN),4,4′-methylene diphenyl diisocyanate and 1,4-bytanediol by the melting one-shot method.The thermal behavior and microphase separation of the polymer were characterized with DSC and TGA.The distance between microphases was estimated from the data of SAXS.Tensile test was used to analyze the effects of different Mn of PCN and content of soft segment on mechanical properties.The results showed that the polymer had partial microphase separation structure, and this structure was less obvious with the increase of the content of soft segment.There were two types of micro-domains in the continuous phase of polycarbonate,the micro-domain formed with urethane and the micro-domain of polycarbonate crystallization itself.There were two obvious stages in its thermal decomposition on which the effect of the content of soft segment was not obvious.With the increase of the content of PCN, the Young’s Modulus decreased and the elongation at break increased.The as-synthesized polycarbonate urethanes(PCNU)showed a maximum tensile strength of 80 MPa.At the same time, elongation at break was more than 400%.
Key words: 聚碳酸酯聚氨酯, 微相分离, 热分解, 力学性能
关键词: 聚碳酸酯聚氨酯, 微相分离, 热分解, 力学性能
GUO Jintang, LIN Fangqian, LIU Bing, ZHAO Meihua. Structure and performance of polycarbonate urethane[J]. CIESC Journal, 2006, 57(7): 1709-1714.
郭锦棠, 林芳茜, 刘冰, 赵美华. 聚碳酸酯聚氨酯的结构及性能 [J]. 化工学报, 2006, 57(7): 1709-1714.
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