Abstract: The aggregation behavior of ionic liquids into micelle was studied.It was found that the micellization of ionic liquids was governed by its side-chain length, head structure and anion species, which could be promoted by increasing hydrophobicity, such as a long side-chain length, a hydrophobic anion or C₂-methylated head.The side-chain length played the most active role in comparison with head group and anion.The micellization of ionic liquids would be weakened with increasing temperature.

摘要： 研究了离子液体在水相中的自聚规律，从侧链、头部及阴离子类型等方面比较了影响胶团聚集的主要因素.实验发现，增加侧链长度有利于胶团形成，降低阴离子水合性以及采用甲基化头部也利于形成胶团，碳链长度变化的作用最明显，升高温度不利于离子液体形成胶团.