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Progress in carbon dioxide sequestration by mineral carbonation

BAO Weijun;LI Huiquan;ZHANG Yi   

  • Online:2007-01-05 Published:2007-01-05

温室气体CO2矿物碳酸化固定研究进展

包炜军;李会泉;张懿   

  1. 中国科学院过程工程研究所绿色过程工程重点实验室;中国科学院研究生院

Abstract: CO2 sequestration by mineral carbonation,namely greenhouse gas CO2 reacting with non-carbonate minerals to form geologically stable mineral carbonates,such as CaCO3,MgCO3,is a new technology for the reduction of carbon dioxide emissions to the atmosphereIn this paper,the optional resources,chemistry,thermodynamics,reaction kinetics as well as mechanisms in the mineral CO2 sequestration were analyzedMoreover,six representative process routes as well as issues of topical interest regarding the investigation of mineral sequestration were reviewedFinally,it was suggested that the integrated indirect process route using industrial solid residues should be a promising option for developing mineral sequestration.

摘要: 将温室气体CO2以碳酸盐(如CaCO3、MgCO3)的固体形式永久储存起来,即CO2矿物碳酸化固定,是减少大气中CO2含量,解除温室效应的一种全新方法。从温室气体CO2矿物碳酸化固定所需的原料、化学及热力学、反应动力学机理等方面,分析了此种方法的特点,同时评述了CO2矿物碳酸化固定的6种典型工艺路线,以及国外有关温室气体CO2矿物碳酸化固定的研究热点。最后指出以工业固体废弃物为原料的间接工艺路线是温室气体CO2矿物碳酸化固定的具有较好应用前景的技术途径。