Abstract: Three perylene derivatives PeryBr、PeryBrAn and PeryAnBp had been synthesized from perylene-3，4，9，10- tetracarboxylic acid bisanhydride. The PeryAnBp was purified by column chromatography on silica，and was characterized by FT-IR，EA，UV/vis and 1H NMR. The result showed that PeryAnBp is a kind of luminescent red material，and the dissolution is improved largely.

摘要： 以苝四羧酸酐为原料，成功合成了1，6，7，12-四溴-苝四酸酐、1，6，7，12-四溴-N，N ′-二苯胺-苝四羧酸二酰亚胺和1，6，7，12-四对叔丁基苯氧基-N，N ′-二苯胺-苝四羧酸二酰亚胺（PeryAnBp）3种化合物。经过柱分离得到较纯净的化合物PeryAnBp，并利用傅里叶红外光谱仪、元素分析仪、紫外可见光谱仪和核磁共振仪对其结构和性质做了表征。结果显示：PeryAnBp为一种红光材料，且其溶解性得到大大的改善。