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GAO Shanbin1,DONG Qun2,CHI Kebin1,3,TAN Mingwei1,LIU Yanfeng1,MENG Xiangbin1
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高善彬1,董 群2,迟克彬3,1,谭明伟1,刘彦峰1,孟祥彬1
Abstract:
The ex-situ presulfidation for hydrogenation catalyst was investigated using H2S and batch reactor with variation in different factors,such as heating rate,quantity of H2S,proportion of H2S with H2,reaction temperature,reaction time,and the partial pressure of inert gas. The effect of presulfidation was evaluated by the sulfur content in catalyst and the bromine value in hydrogenation product. Suitable reaction conditions were found as the heating rate of 2 ℃/min,3 h of reaction at 230 ℃,1∶1 proportion of H2S with H2,1 h of final reaction at 340 ℃,in which the quantity of H2S was 1.3 times of theoretical value and the partial pressure of inert gas was 1.5 MPa. The results indicated that this technology is feasible and the activity of ex-situ presulfidation catalyst using batch reactor is better than that of the in-situ process.
摘要:
利用间歇釜反应器,以H2S为硫化介质,研究了升温速率、H2S用量、H2S和H2体积比、反应温度、反应时间、惰性气体分压等工艺条件对裂解汽油二段加氢催化剂器外预硫化效果的影响。以硫化度和加氢产品溴价作为硫化效果评价指标,确定适宜的工艺条件为:升温速率2 ℃/min,230 ℃恒温时间3 h,H2S和H2配比1∶1,H2S用量为理论用量的1.3倍,反应终温340 ℃,终温恒温时间1 h,惰性气体分压1.5 MPa。实验结果表明,加氢催化剂间歇釜器外预硫化是可行的,效果优于器内预硫化。
GAO Shanbin1,DONG Qun2,CHI Kebin1,3,TAN Mingwei1,LIU Yanfeng1,MENG Xiangbin1. Presulfidation with H2S for hydrogenation catalyst by batch reactor[J]. .
高善彬1,董 群2,迟克彬3,1,谭明伟1,刘彦峰1,孟祥彬1. 以H2S为硫化介质的加氢催化剂间歇釜器外预硫化工艺 [J]. CIESC Journal.
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https://hgxb.cip.com.cn/EN/Y2010/V29/I9/1654