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Progress in energetic aminotetrazole compounds

LI Fang,DU Zhiming   

  1. State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology,Beijing 100081,China
  • Online:2011-11-21 Published:2011-11-05

氨基四唑含能化合物研究进展

李 芳,杜志明   

  1. 北京理工大学爆炸科学与技术国家重点实验室,北京 100081

Abstract:

Aminotetrazole is an organic substance with the highest nitrogen contentwhich exhibits high positive formation enthalpy and good thermal stability. It has potential applications in the field of solid propellantsgas generationshigh energy insensitivity explosives and non-smoke pyrotechnics. In this paperthe synthesis and properties of 5-aminotetrazolates and 1,5-diaminotetrazolates are reviewed. The development tendency for energetic compounds of aminotetrazole is also prospected.

摘要:

氨基四唑是有机物中含氮量最高的一类化合物,具有高的正生成焓和良好的热力学稳定性,在高能钝感炸药、气体发生剂、无烟烟火剂、固体推进剂等领域有着广泛的应用前景。氨基四唑主要包括分子化合物、离子化合物和配合物3种。本文综述了5-氨基四唑和1,5-二氨基四唑类含能化合物的合成及性能。在此基础上,分析了氨基四唑类含能化合物的未来发展趋势。