Abstract: The domestic and overseas research progress of synthesizing nano-structured conducting polymers by using block copolymers as templates was reviewed. Nano-structured conducting polymers novel functional materials have become a hot research topic in recent years. Using block copolymers as templates is the most promising method of synthesizing this kind of materials. Therefore, the forming mechanism, experimental methods and influence factors of synthesizing nano-structured conducting polymers with regular morphology by this method were summarized. At the end, the problems existing in the research of nano-structured conducting polymers were presented. Using block copolymer as template would be beneficial to improving the controllability of the morphology and size of conducting polymers, and thus to improve such properties of conducting polymers as solubility, processability and conductivity.

Key words: block copolymer template, nano-structure, conducting polymer

摘要： 简述了以嵌段共聚物为模板合成纳米结构导电聚合物材料的国内外发展状况。近年来，纳米结构导电聚合物材料作为极具研究价值的新型功能材料而成为了材料科学的研究热点。以嵌段共聚物为模板则是制备此类材料最有前途的方法之一。本文详细地总结并归纳了通过该方法制备形貌规整的纳米级导电聚合物材料的成形机理、实验方法及其影响因素等。最后总结了纳米结构导电聚合物材料相关研究中存在的诸多问题，并简要指出以嵌段共聚物为模板有助于提高导电高聚物的形貌及尺寸的可控性，进而有助于改善导电高聚物的溶解性、加工性能、电导率等各项性能，也将有利于拓宽导电高聚物在纳米科技领域中的应用前景。

关键词: 嵌段共聚物模板, 纳米结构, 导电聚合物