Oxidative esterification of methacrolein to methyl methacrylate over Pd-Pb/Al2O3 catalysts

Abstract

Abstract: The Pd-Pb catalyst supported on Al2O3 was prepared by the two-step impregnation method.The oxidative esterification of methacrolein (MAL) to methyl methacrylate (MMA) was carried out in a stainless bubble autoclave over the catalyst.The influences of the reaction conditions on catalytic activity were investigated in detail.The optimal reaction conditions were as follows: T=80℃, P=0.3 MPa, methanol∶MAL=8∶1 ( molar ratio ), catalyst mass concentration in the reaction system 3.84%, pH of the reaction system 7—8, oxygen flux rate 30 ml•min^-1.Under the above conditions,MAL conversion and MMA selectivity reached 91% and 84%, respectively.The catalyst was recycled for seven times and still kept good selectivity.

Key words: 甲基丙烯醛, 甲基丙烯酸甲酯, 氧化酯化

关键词: 甲基丙烯醛, 甲基丙烯酸甲酯, 氧化酯化

DONG Haifeng, LI Zengxi, WANG Zhengping, CHENG Weiguo, ZHAO Wei, ZHANG Xiangping, ZHANG Suojiang . Oxidative esterification of methacrolein to methyl methacrylate over Pd-Pb/Al₂O₃ catalysts[J]. CIESC Journal, 2006, 57(6): 1346-1350.

董海峰, 李增喜, 王正平, 成卫国, 赵威, 张香平, 张锁江. Pd-Pb/Al₂O₃催化剂上甲基丙烯醛氧化酯化合成甲基丙烯酸甲酯 [J]. 化工学报, 2006, 57(6): 1346-1350.

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Oxidative esterification of methacrolein to methyl methacrylate over Pd-Pb/Al₂O₃ catalysts

Pd-Pb/Al₂O₃催化剂上甲基丙烯醛氧化酯化合成甲基丙烯酸甲酯

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