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MODELING OF UNSTEADY-STATE OXIDATION PROCESS OF SO_2 (Ⅰ) AXIAL HEAT TRANSFER OF FIXED-BED PACKED WITH VANADIUM CATALYST

Wu Huixiong, Zhang Shuzeng, Li Chengyue and Fu Jufu{Department of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029)   

  • Online:1995-08-25 Published:1995-08-25

二氧化硫强制动态氧化过程的模型化(Ⅰ)——钒催化剂固定床的轴向传热特性

吴慧雄,张树增,李成岳,傅举孚   

  1. 北京化工大学化工系!北京100029,北京化工大学化工系!北京100029,北京化工大学化工系!北京100029,北京化工大学化工系!北京100029

Abstract: By applying the technique of pulse thermal input, the axial heat transfer of a fixed -bed packed with vanadium catalyst was investigated under the conditions that the initial temperature ranged from room temperature to about 500℃, and Re=30~660. It was shown that the correlations for calculating ke,ax and hp presented by Wakao are still applicable to the cases studied here at an average bed temperature under 200℃ but the values of axial thermal conductivity at about 500℃ are higher than those predicted previously.

摘要: 利用热响应技术对装填S101型钒催化剂的固定床轴向传热特性进行了实验研究。实验范围是:床层初始温度从室温至约500℃,Re=30~660,大体上覆盖了工业反应器的操作条件。结果表明,在床层温度小于200℃的低温下,前人已提出的计算a_(ax)和Nu数的公式仍然适用,但在更高的温度下,轴向有效导热系数的数值比前人的预测要大。

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