化工学报 ›› 2021, Vol. 72 ›› Issue (2): 1132-1141.DOI: 10.11949/0438-1157.20200972

• 能源和环境工程 • 上一篇    下一篇

燃煤烟气脱硝副产物硫酸氢铵/硫酸铵沉积与分解特性研究

卿梦霞1(),张鑫1,刘亮1,张巍1,王乐乐3,苏胜2,孔凡海3,向军2()   

  1. 1.长沙理工大学能源与动力工程学院,湖南 长沙 410114
    2.华中科技大学煤燃烧国家重点实验室,湖北 武汉 430074
    3.西安热工研究有限公司苏州分公司,江苏 苏州 215153
  • 收稿日期:2020-07-20 修回日期:2020-08-10 出版日期:2021-02-05 发布日期:2021-02-05
  • 通讯作者: 向军
  • 作者简介:卿梦霞(1993—),女,博士,讲师,qingmx@csust.edu.cn
  • 基金资助:
    国家自然科学基金项目(51976072)

Study on deposition and decomposition characteristics of ammonium bisulfate/ammonium sulfate as by-product of denitration in coal-fired flue gas

QING Mengxia1(),ZHANG Xin1,LIU Liang1,ZHANG Wei1,WANG Lele3,SU Sheng2,KONG Fanhai3,XIANG Jun2()   

  1. 1.School of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410114, Hunan, China
    2.State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China
    3.Xi’an Thermal Power Research Institute Company, Limited, Suzhou Branch, Suzhou 215153, Jiangsu, China
  • Received:2020-07-20 Revised:2020-08-10 Online:2021-02-05 Published:2021-02-05
  • Contact: XIANG Jun

摘要:

搭建模拟空预器多段控温实验台,研究不同SO3浓度、SO3/NH3比、不同温度下硫酸氢铵(ABS)与硫酸铵(AS)的生成、沉积与分解特性。在高温条件下发生的初始沉积部位,沉积物均为液态ABS,其失重特性与纯ABS基本一致。而在低温条件下,则根据SO3/NH3比的不同沉积物特性有所变化。SO3/NH3比为2∶1时,沉积物为H2O、H2SO4与少量ABS的混合物,以密集液滴形态存在,呈多段分解特性;SO3/NH3比为1∶1与1∶2时,沉积物为分散性较强的干AS粉末,分解特性与纯AS基本一致。研究结果可为ABS防控提供指导。

关键词: 烟气脱硝, SO3, 硫酸氢铵, 硫酸铵, 空气预热器

Abstract:

A special multi-stage temperature control experimental bench for simulated air preheater was built, and the generation, deposition and decomposition of ammonium bisulfate (ABS) and ammonium sulfate (AS) under different SO3 concentrations, SO3/NH3 ratio, and different temperature conditions were studied. At the initial deposition site under high temperature conditions, the deposits are all liquid ABS, and its weight loss characteristics are basically the same as pure ABS. However, under lower temperature ranges, the characteristics of the sediments will change with SO3/NH3. When SO3/NH3 is 2∶1, the sediments are the mixture of H2O, H2SO4 and a small amount of ABS, which exists in the form of dense droplets, and it has multi-stage decomposition characteristics. When SO3/NH3 is 1∶1 and 1∶2, the sediments are the dry AS power with strong dispersion, and its decomposition characteristics are basically the same as pure AS. The results can provide guidance for ABS prevention and control.

Key words: denitration, SO3, ammonium bisulfate, ammonium sulfate, air preheater

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