CIESC Journal

• 化工学报 • 上一篇    下一篇

在多孔介质内气体扩散的分形表征

张宝泉,李绍芬,廖晖   

  1. 天津大学化学工程系!天津300072,天津大学化学工程系!天津300072,天津大学化学工程系!天津300072
  • 出版日期:1994-06-25 发布日期:1994-06-25

FRACTAL CHARACTERISTIC OF GAS DIFFUSION IN POROUS MEDIA

Zhang Baoquan,Li Shaofen and Liao Hui(Department of Chemical Engineering, Tianjin University, Tianjin 300072)   

  • Online:1994-06-25 Published:1994-06-25

摘要: 将多孔介质内孔抽象为分形曲线,并以该曲线的维数作为多孔介质的结构参数—谱维数d,藉此建立了气体在介质内的扩散通量计算式,并给出了测量分形结构码尺的计算方程和多孔介质谱维数的测定方法.由双组分气体在Ni/r- Al_2O_3催化剂上的扩散实验数据,计算出该催化剂的谱维数d=1.10.

Abstract: The pore inside porous media is abstracted into a fractal curve after analysis in this paper. The fractality of the fractal curve is defined as a spectral or fracton dimension d , the value of which is in the range 1≤ d< 2 . According to a scaling relation that relates the real length of a fractal curve to its shadow and yardstick size, an equation of diffusion flux for two - component gas mixtures in porous media is deducedwhich can also be used to measure d in terms of experimental data of diffusion.After presenting a practical equation calculating the yardstick size in this case, the method to determine d is subsequently offered. The above procedure is applied to Ni /γ-Al2O3 catalyst . The result of calculation shows that the internal pores of catalyst Ni /γ-Al2O3 can be featured as a fractal with respect to gaseous diffusion processes with its spectral or fracton dimension d = 1. 10.

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