Abstract: The laboratory scale experiments for determining the influence on the distribution of phosphorus by.adding Al-containing component in melting furnace were conducted. It is found that the addition of Al-containing component in melting furnace increased the amount of phosphorus in slag phase. Thermodynamic analysis of the industrial sludge melting process with the addition of different Al-containing components was also carried out. The compositions of slag and the gas in three different zones in melting furnace were obtained. The results also demonstrate that increasing the mole ratio Al/P of charged materials is an effective way to fix more phosphorus in slap, which can help reduce the amount of H3PO4 precipitate from guy in the waste heat boiler later.