化工学报 ›› 2006, Vol. 57 ›› Issue (7): 1588-1590.

• 催化、动力学与反应器 • 上一篇    下一篇

在1-乙基咪唑三氟乙酸盐离子液体中合成的聚吡咯对草酸的电催化氧化

李美超;沈振陆;马淳安;高云芳   

  1. 浙江工业大学化材学院
  • 出版日期:2006-07-25 发布日期:2006-07-25

Electro-oxidation of oxalic acid with polypyrrole prepared in 1-ethylimidazolium trifluoroacetate

LI Meichao;SHEN Zhenlu;MA Chun’an;GAO Yunfang   

  • Online:2006-07-25 Published:2006-07-25

关键词: 草酸, 聚吡咯, 1-乙基咪唑三氟乙酸盐

Abstract: The electrochemical oxidation of oxalic acid is important in environmental engineering.In this paper,polypyrrole(PPy)was prepared galvanostatically in an ionic liquid 1-ethylimidazolium trifluoroacetate(HEImTfa)and its electro-catalysis function for the electrochemical oxidation of oxalic acid was investigated by using cyclic voltammetry.The results showed that the electro-catalytic activity of PPy prepared in HEImTfa(PPy-HEImTfa)was greatly improved as compared with that prepared in conventional H2SO4 aqueous solution.Therefore,the use of HEImTfa as growth electrolyte and solvent for electro-polymerization of pyrrole resulted in an electrochemically catalytic film of PPy for the electro-oxidation of oxalic acid.

Key words: 草酸, 聚吡咯, 1-乙基咪唑三氟乙酸盐