化工学报 ›› 2008, Vol. 59 ›› Issue (11): 2935-2940.

• 材料化学工程与纳米技术 • 上一篇    下一篇

α-烯基聚醚磺酸盐的耐盐性能及应用

辛寅昌;邱增中;张盛军;郑平;赵明方   

  1. 山东师范大学化学化工与材料科学学院;吐哈石油勘探开发指挥部
  • 出版日期:2008-11-05 发布日期:2008-11-05

Salt-resistance property and application of α-olefine polyether sulfonate

XIN Yinchang;QIU Zengzhong;ZHANG Shengjun;ZHENG Ping;ZHAO Mingfang   

  • Online:2008-11-05 Published:2008-11-05

摘要:

以不饱和醇作引发剂利用双金属氰化物(DMC)催化加成共聚环氧丙烷、环氧乙烷,然后磺化中和成盐,研制出一种耐盐活性剂。该活性剂的耐受矿化度范围为2000~150000 mg•L-1。该活性剂不仅能把高矿化度水的表面张力从80.5 mN•m-1(30℃)降到37.1 mN•m-1(30℃),而且即使水中的Ca2+、Mg2+浓度高达10000 mg•L-1时,其表面活性剂水溶液也是无色透明的,没有任何沉淀和絮状物。在某油田稠油水中矿化度高达150000 mg•L-1的稠油降黏实验中发现,该活性剂能使含水稠油黏度从85000 mPa•s(30℃)降到14 mPa•s(30℃),并且还能使脱水后的原油本体黏度降低一半以上。

关键词: α-烯基聚醚, 耐盐活性剂, 高矿化度, 耐盐

Abstract:

Epoxyethylene and epoxypropylene were polymerized by double metal cyanide (DMC) with unsaturated alcohol as initiator.The obtained polyether was sulfonated, and neutralized to prepare a salt-resisting surfactant.The surfactant resisted water salinity in a range of 2000 mg•L-1 to 150000 mg•L-1.In addition, the surfactant exhibited significant effect on reducing the surface tension of high salinity water from 80.5 mN•m-1 to 37.1 mN•m-1 at 30℃.Moreover, even when the concentration of calcium or magnesium cations in the water reached 10000 mg•L-1, the surfactant solution remained colorless and transparent without deposition and flocculation.The experiment in oil field indicated that the salt-resisting surfactant reduced the viscosity of water-containing heavy oil from 85000 mPa•s to 14 mPa•s.After demulsification, the intrinsic viscosity of the dewatered crude oil decreased by half.

Key words: α-烯基聚醚, 耐盐活性剂, 高矿化度, 耐盐