化工学报 ›› 2023, Vol. 74 ›› Issue (2): 916-923.DOI: 10.11949/0438-1157.20221020
收稿日期:
2022-07-25
修回日期:
2023-01-11
出版日期:
2023-02-05
发布日期:
2023-03-21
通讯作者:
单国荣
作者简介:
靳志远(1998—),男,硕士研究生,zhiyuanjin@zju.edu.cn
Zhiyuan JIN1,2(), Guorong SHAN2,3(), Pengju PAN2,3
Received:
2022-07-25
Revised:
2023-01-11
Online:
2023-02-05
Published:
2023-03-21
Contact:
Guorong SHAN
摘要:
我国油田已全面进入三次采油阶段,研制适应高温高盐开采环境下的驱油剂受到广泛关注。针对传统聚丙烯酰胺类驱油剂进行了改性,采用水溶液聚合的方法,制备并优化了丙烯酰胺/2-丙烯酰胺基-2-甲基-1-丙烷磺酸/对苯乙烯磺酸钠(AM/AMPS/SSS)三元共聚物,探究了各种反应条件对产物水溶液表观黏度的影响,总结分析了相关规律,得到最优的共聚物制备条件。使用旋转黏度计,对聚合物溶液的表观黏度、耐温耐盐性能进行了研究,最终得到了耐温、耐盐效果明显,热稳定性良好的AM/AMPS/SSS三元共聚物,在目前严峻的原油开采环境中有较好的应用前景。
中图分类号:
靳志远, 单国荣, 潘鹏举. AM/AMPS/SSS三元共聚物的制备及耐温耐盐性能[J]. 化工学报, 2023, 74(2): 916-923.
Zhiyuan JIN, Guorong SHAN, Pengju PAN. Preparation and heat and salt resistance of AM/AMPS/SSS terpolymer[J]. CIESC Journal, 2023, 74(2): 916-923.
Initiator concentration | Monomer mass ratio (AM∶AMPS∶SSS) | Monomer concentration | System pH | Polymerization temperature |
---|---|---|---|---|
0.2%(mass) | 4∶1∶0.1 | 20%(mass) | 7 | 40℃ |
表1 初始反应条件
Table 1 Initial reaction conditions
Initiator concentration | Monomer mass ratio (AM∶AMPS∶SSS) | Monomer concentration | System pH | Polymerization temperature |
---|---|---|---|---|
0.2%(mass) | 4∶1∶0.1 | 20%(mass) | 7 | 40℃ |
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