1,6-己二胺对碳微球的功能化修饰

doi:10.3969/j.issn.0438-1157.2012.10.049

化工学报 ›› 2012, Vol. 63 ›› Issue (10): 3350-3357.DOI: 10.3969/j.issn.0438-1157.2012.10.049

• 材料化学工程与纳米技术 • 上一篇下一篇

1,6-己二胺对碳微球的功能化修饰

杨永珍^1,2, 宋静静^1,3, 李勇^1,3, 刘旭光^1,4, 许并社^1,2

1. 新材料界面科学与工程教育部重点实验室(太原理工大学), 山西太原 030024;
2. 太原理工大学新材料工程技术研究中心, 山西太原 030024;
3. 太原理工大学材料科学与工程学院, 山西太原 030024;
4. 太原理工大学化学化工学院, 山西太原 030024

收稿日期:2012-01-17 修回日期:2012-04-19 出版日期:2012-10-05 发布日期:2012-10-05
通讯作者: 刘旭光
作者简介:刘旭光,杨永珍(1969- ),女,博士,副教授。
基金资助:
长江学者与创新团队发展计划项目(IRT0972);国家自然科学基金项目(51152001,21176169,20971094,51002102);国家教育部博士点基金项目(20101402110007);山西省国际科技合作项目(2010081017)。

Functional modification of carbon microspheres by 1,6-hexanediamine

YANG Yongzhen^1,2, SONG Jingjing^1,3, LI Yong^1,3, LIU Xuguang^1,4, XU Bingshe^1,2

1. Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
2. Research Center for Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
3. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
4. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

Received:2012-01-17 Revised:2012-04-19 Online:2012-10-05 Published:2012-10-05
Supported by:
supported by the Program for Changjiang Scholar and Innovative Research Team in University(IRT0972),the National Natural Science Foundation of China(51152001,21176169,20971094,51002102),the Ph.D.Programs Foundation of Ministry of Education of China(20101402110007)and the International S&T Co-operation Program of Shanxi Province(2010081017).

摘要/Abstract

摘要： 首先采用体积比为1:3的浓硝酸和浓硫酸对碳微球(CMSs)进行氧化修饰,改善其表面活性;然后在缩合剂N,N'-二环己基碳二亚胺(DCC)的作用下,用1,6-己二胺与氧化CMSs反应,制备胺化CMSs。在胺化过程中考虑缩合剂DCC用量、反应时间和反应温度的影响。采用场发射扫描电子显微镜、热重分析仪和红外光谱仪对各阶段产物进行了形貌和结构的表征与分析。结果表明:对于0.3 g氧化CMSs,DCC用量0.3 g、反应时间36 h和反应温度110℃是胺化反应的适宜条件,所得胺化产物在弱极性溶剂乙酸乙酯和氯仿中有良好的分散性,且能与常用聚合物给体材料(聚3-己基噻吩)能级匹配,有望进一步与聚合物复合,为制备聚合物太阳能电池奠定基础。

关键词: 碳微球, 1,6-己二胺, 胺化, 修饰

Abstract: Carbon microspheres(CMSs)were oxidized by a mixture of concentrated sulfuric acid and nitric acid(volume ratio of 1:3)to improve their surface activity.Then,the oxidized CMSs reacted with 1,6-hexanediamine to prepare aminated CMSs with N,N'-dicyclohexyl carbodiimide(DCC)as condensation agent.The influences of DCC dosage,reaction time and temperature were studied.The morphology and structure of the products were characterized by field emission scanning electron microscopy,thermogravimetry and Fourier transformation infrared spectrometry.The results showed that the preferable DCC dosage,amination time and temperature were 0.3 g,36 h,110℃ for 0.3 g of oxidized CMSs.The surface-aminated CMSs had good dispersion in low-polar solvents i.e.ethyl acetate and chloroform,and energy levels were matchable with the most commonly used electron-donor,poly(3-hexylthiophene).The composites from the aminated CMSs and poly(3-hexylthiophene)would lay the foundation for preparation of polymer solar cells.

Key words: carbon microspheres, 1,6-hexanediamine, amination, modification

中图分类号:

TB332

杨永珍, 宋静静, 李勇, 刘旭光, 许并社. 1,6-己二胺对碳微球的功能化修饰[J]. 化工学报, 2012, 63(10): 3350-3357.

YANG Yongzhen, SONG Jingjing, LI Yong, LIU Xuguang, XU Bingshe. Functional modification of carbon microspheres by 1,6-hexanediamine[J]. CIESC Journal, 2012, 63(10): 3350-3357.

参考文献 22

[1]	Zhang Tianhui(张天慧),Piao Lingyu(朴玲钰),Zhao Suling(赵谡玲),Xu Zheng(徐征),Yang Lei(杨磊),Liu Xiangzhi(刘祥志),Ju Siting(鞠思婷).New progress in study of organic solar cell materials[J].Journal of Chinese Journal of Organic Chemistry(有机化学),2011,31(2):260-272
[2]	Tian Na(田娜),Ma Xiaoyan(马晓燕),Wang Yifei(王毅霏),Zhu Xiaobo(朱小波),Li Dongmei(李冬梅).Research progress on the structure and materials of photosensitive layer of polymer solar cells[J].Polymer Bulletin(高分子通报),2011(2):85-91
[3]	Liang Changxin(梁昌鑫),Chen Xiaoqi(陈孝祺).Status quo and developing trend of solar energy[J].Journal of Shanghai Dianji University(上海电机学院学报),2010,13(3):182-186
[4]	Zhu H W,Wei J Q,Wang K L,Wu D H.Applications of carbon materials in photovoltaic solar cells[J].Sol. Energy Mater. Sol.Cells,2009,93(9):1461-1470
[5]	Yu Zhexun(于哲勋),Li Dongmei(李冬梅),Qin Da(秦达),Sun Huicheng(孙惠成),Zhang Yiduo(张一多),Luo Yanhong(罗艳红),Meng Qingbo(孟庆波).Research and development of dye-sensitized solar cells[J].Materials China(中国材料进展),2009,28(7/8):8-15
[6]	Yu G,Gao J,Hummelen J C,Wudl F,Heeger A J.Polymer photovoltaic cells:enhanced efficiencies via a network of internal donor-acceptor heterojunctions[J].Science,1995,270(5243):1789-1791
[7]	He Y J,Chen H Y,Hou J H,Li Y F.Indene-C60 bisadduct:a new acceptor for high-performance polymer solar cells[J].J. Am. Chem. Soc.,2010,132(4):1377-1382
[8]	Xu B S,Han P D,Liang J,Liu X G,Bao H Q,Li T B,Chen M W.Theoretical investigation of the reflectivity of fullerene-(C60,C70)/AlN multilayers in UV region[J].Solid State Communications,2005,133(6):353-356
[9]	Zhang Z X,Han P D,Liu X G,Zhao J F,Jia H S,Zeng F G,Xu B S.First principle calculations of the electronic properties of the fullerene derivative as an electron acceptor in organic solar cells[J].J. Phys. Chem. C,2008,112(48):19158-19161
[10]	Xu B S,Chen L Q,Liu X G,Zhou H F,Xu H X,Fang X H,Wang Y L.Mixed ligands 8-hydroxyquinoline aluminum complex with high electron mobility for organic light-emitting diodes[J].Appl. Phys. Lett.,2008,92(10):103305-103307
[11]	Yang Yongzhen(杨永珍),Liu Weifeng(刘伟峰),Han Yanxing(韩艳星),Liu Xuguang(刘旭光),Xu Bingshe(许并社).Self-assembly film of functionlized carbon microspheres[J].Materials China(中国材料进展),2011,30(2):56-60
[12]	Yang Yongzhen(杨永珍),Han Yanxing(韩艳星),Li Sha(李莎),Liu Hongyan(刘红艳),Liu Xuguang(刘旭光),Xu Bingshe(许并社).Surface modification of carbon microspheres by ionization[J].CIESC Journal(化工学报),2010,61(10):2662-2666
[13]	Li Sha(李莎),Duan Feifei(段菲菲),Yang Yongzhen(杨永珍),Liu Xuguang(刘旭光),Xu Bingshe(许并社).Surface modification of carbon microspheres using a silane couping agent[J].Journal of Functional Materials(功能材料),2011,42(1):25-29
[14]	Cao Chunhua(曹春华),Li Jialin(李家麟),Jia Zhijie(贾志杰),Chen Zhenghua(陈正华).Decoration of carbon nanotubes with amine group by reaction with diamine[J].New Carbon Materials(新型炭材料),2004,19(2):137-140
[15]	Contreras-Torres F F,Ochoa-Olmos O E,Basiuk E V.Amine-functionalized multi-walled carbon nanotubes:an atomic force microscopy study[J].J. Scann. Probe. Microsc.,2009,4(2):100-106
[16]	González-Domínguez J M,González M,Ansón-Casaos A,Díez-Pascual A M,Gómez M A,Martínez M T.Effect of various aminated single-walled carbon nanotubes on the epoxy cross-linking reactions[J].J. Phys. Chem. C,2011,115:7238-7248
[17]	Wladyka-Przybylak M,Wesolek D,Gieparda W,Boczkowska A,Ciecierska E.The effect of the surface modification of carbon nanotubes on their dispersion in the epoxy matrix[J].Pol. J. Chem. Tech.,2011,13(2):62-68
[18]	Wang Xuemei(王雪梅).Study on the synthesis and properties of fullerene derivative electron transport functional materials.Dalian:Dalian University of Technology,2009
[19]	Wang Yantao(王彦涛),Wei Wei(韦玮),Liu Junfeng(刘俊峰),Zhang Hui(张辉).Research results of polymer bulk heterojunction solar cell[J].Polymer Bulletin(高分子通报),2004(2):9-14
[20]	Zhou Xiaoping(周小平),Yu Lamei(余腊妹),Guo Qiaohui(郭乔辉),Zhou Zhengping(周政平),Hou Haoqing(侯豪情).Surface modification of multiwalled carbon nanotubes and their dispersion in solvents[J].New Chemical Materials(化工新型材料),2009,37(6):61-62
[21]	Li Yongfang(李永舫).High efficiency conjugated polymer donor and fullerene derivative acceptor photovoltaic materials for polymer solar cells[J].Polymer Bulletin(高分子通报),2011(10):33-49
[22]	Liu Z K,Li J H,Sun Z H,Tai G,Lau S P,Yan F.The application of highly doped single-layer graphene as the top electrodes of semitransparent organic solar cells[J].ACS Nano.,2012,6(1):810-818

1,6-己二胺对碳微球的功能化修饰

Functional modification of carbon microspheres by 1,6-hexanediamine

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