金属有机框架孔径调控进展

doi:10.11949/0438-1157.20190801

化工学报 ›› 2020, Vol. 71 ›› Issue (2): 429-450.DOI: 10.11949/0438-1157.20190801

金属有机框架孔径调控进展

原野¹(),王明²,周云琪¹,王志¹(),王纪孝¹

^1.天津大学化工学院化学工程研究所，天津市膜科学与海水淡化技术重点实验室，化学工程联合国家重点实验室（天津大学），天津化学化工协同创新中心，天津 300350
^2.滨州学院化工与安全学院，山东省工业污水资源化工程技术研究中心，山东，滨州 256600

收稿日期:2019-07-11 修回日期:2019-09-18 出版日期:2020-02-05 发布日期:2020-02-05
通讯作者: 王志
作者简介:原野（1995—），男，硕士研究生，tjuyuanye@tju.edu.cn
基金资助:
国家重点研发计划项目(2017YFB0603400);国家自然科学基金重点项目(21436009);化学工程联合国家重点实验室自主研究课题(SKL-ChE-18T02)

Progress in pore size regulation of metal-organic frameworks

Ye YUAN¹(),Ming WANG²,Yunqi ZHOU¹,Zhi WANG¹(),Jixiao WANG¹

^1.Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University; Tianjin Key Laboratory of Membrane Science and Desalination Technology; State Key Laboratory of Chemical Engineering (Tianjin University); Tianjin Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300350, China
^2.Department of Chemical Engineering and Safety, Binzhou University; Shandong Engineering Research Center for Industrial Wastewater Resources Reuse, Binzhou 256600, Shandong, China

Received:2019-07-11 Revised:2019-09-18 Online:2020-02-05 Published:2020-02-05
Contact: Zhi WANG

摘要/Abstract

摘要：

金属有机框架(MOFs)以其可灵活调节的孔道结构、大孔隙率和大比表面积等特点受到广泛关注。设计并构建能够实现目标功能的、具有合适孔径分布的MOFs材料关系到MOFs材料在分离、催化以及质子传导等领域中的应用。综述了MOFs材料孔径的主要调控方法，包括原位合成调控、后合成修饰调控、穿插调控以及辅助合成调控，总结了四种调控方法的特点和不足，并对未来MOFs孔径调控的发展方向进行了展望。

关键词: 金属有机框架, 孔径, 原位合成, 后合成修饰, 穿插调控, 辅助合成

Abstract:

Metal-organic frameworks (MOFs) have attractecl wide attention due to their flexible pore structure, large porosity and specific surface area. Designing and constructing MOFs with suitable pore size distribution to achieve the desired function is related to the application of MOFs in the fields of separation, catalysis, proton conduction, etc. In this paper, the main methods of regulating MOFs pore size are reviewed, including in-situ synthesis, post-synthesis modification, intercalation regulation and auxiliary synthesis. The characteristics and shortcomings of the four regulation methods are summarized, and the future direction of MOFs pore size regulation is also prospected.

Key words: metal-organic frameworks, pore size, in-situ synthesis, post-synthetic modification, interpenetrating regulation, auxiliary synthesis

中图分类号:

TQ 028.8

原野, 王明, 周云琪, 王志, 王纪孝. 金属有机框架孔径调控进展[J]. 化工学报, 2020, 71(2): 429-450.

Ye YUAN, Ming WANG, Yunqi ZHOU, Zhi WANG, Jixiao WANG. Progress in pore size regulation of metal-organic frameworks[J]. CIESC Journal, 2020, 71(2): 429-450.

图/表 1

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金属有机框架孔径调控进展

Progress in pore size regulation of metal-organic frameworks

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