化工学报 ›› 2008, Vol. 59 ›› Issue (6): 1454-1461.

• 过程系统工程 • 上一篇    下一篇

乙炔加氢反应器二维非均相机理动态建模及分析

罗雄麟;刘建新;许锋;左信   

  1. 中国石油大学自动化研究所
  • 出版日期:2008-06-05 发布日期:2008-06-05

Heterogeneous, two-dimensional dynamic modeling and analysis of acetylene hydrogenation reactor

LUO Xionglin;LIU Jianxin;XU Feng;ZUO Xin   

  • Online:2008-06-05 Published:2008-06-05

摘要:

乙炔加氢反应器具有非线性、慢时变的特点,当前用于预测控制的模型过于简化,使得对反应器长期运行的控制效果难以达到最佳,因此有必要建立精确的模型作为乙炔加氢反应器的实验室虚拟装置,研究更加有效的控制方法。通过机理分析的方法建立了乙炔加氢反应器严格的二维非均相动态数学模型,并且考虑了催化剂失活的问题。基于动态流程模拟软件gPROMS分析了重要模型参数对反应器稳态模拟的影响,为不同的装置选择参数提供了依据,并且针对本文模拟的实际对象提供了一组数据。模拟分析了催化剂失活对于系统长期运行的影响。对所建立的动态数学模型进行了动态模拟,结果基本反映了实际生产情况。将动态机理模型线性化,得到动态机理模型在不同操作点上的线性状态空间模型特征值,以此进行稳定性分析。动态模拟和稳定性分析的结果表明,在反应温度控制开环的条件下,所研究的反应器在大范围的操作点是稳定的。

关键词:

乙炔加氢反应器, 非均相, 动态模拟, 参数分析, 稳定性分析

Abstract:

The industrial acetylene hydrogenation system has the characteristics of nonlinearity and slow parameter variance.The model, which is applied to model predictive control currently, is so simple that the predictive control result could not achieve the optimal effect during a long-term operation.So it is necessary to establish an accurate model of reactor as the virtual instrument in laboratory.Based on the model, it is possible to further study the more effective control method.In this paper, a heterogeneous, two-dimensional and dynamic model for an industrial acetylene hydrogenation system was developed through process analysis.The condition for activity loss with time, due to hydrocarbon deposition resulting from acetylene green oils, was also considered.The dynamic process simulation software gPROMS was utilized to perform its simulation, and the dynamic process could predict the changing trend.The effects of important parameters on the system simulation were analyzed, and a group of parameter values were chosen for the reactor which was studied in this paper.By linearizing the dynamic model at different operation points, the different latent roots of the linear state space model were obtained and used to analyze the system stability at different operation points.The simulation and stability analysis showed that the reactor was under control.

Key words:

乙炔加氢反应器, 非均相, 动态模拟, 参数分析, 稳定性分析